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Ultralow temperature discharge electrolyte of novel lithium ion battery

A lithium-ion battery and electrolyte technology, applied in the field of lithium-ion batteries, can solve problems such as poor battery performance

Inactive Publication Date: 2014-03-19
HUARUI XINXIANG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, it is difficult for commercialized lithium-ion batteries to meet the needs of important fields such as electric vehicles, aerospace technology, and military affairs. One of the main reasons is that the performance of batteries is not good at high and low temperatures. A broadening of the working temperature agenda is the focus of lithium-ion batteries. key issues

Method used

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  • Ultralow temperature discharge electrolyte of novel lithium ion battery

Examples

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Embodiment 1

[0019] The mass percentage is 2% fluoropropylene carbonate and 11% lithium hexafluorophosphate dissolved in 87% organic solvent (the mass ratio of propylene carbonate, ethylene carbonate, ethyl methyl carbonate and ethyl formate is 1:4:4:4 ), mix well to make electrolyte.

Embodiment 2

[0021] The mass percentage is 3% monofluoromethyl ethylene carbonate and 13% lithium hexafluorophosphate dissolved in 84% organic solvent (the mass ratio of propylene carbonate, ethylene carbonate, ethyl methyl carbonate and ethyl formate is 1:4: 4:4), mix well to make electrolyte.

Embodiment 3

[0023] The mass percent is that 5% of 4-trifluoromethylethylene carbonate and 13.5% of lithium hexafluorophosphate are dissolved in 81.5% of organic solvents (propylene carbonate, ethylene carbonate, methyl ethyl carbonate and ethyl formate mass ratio are 1: 4:4:4), mix well to make electrolyte.

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Abstract

The invention relates to ultralow temperature discharge electrolyte of a novel lithium ion battery. The electrolyte comprises the following raw materials in percent by weight: component A, namely 10-15 percent of conductive lithium salt, component B, namely 80-90 percent of organic solvent and component C, namely 2-8 percent of additive. The electrolyte has extremely high electrochemical stability. The freezing point is lowered, the ion migration capability is improved, the electrical conductivity is improved, the lithium ion transfer resistance is reduced, and the wettability of the electrolyte on a diaphragm under low-temperature conditions and the penetrability of the lithium ion to the diaphragm are improved. Therefore, the electrolyte has the characteristics of being capable of normally working in an environment with temperature of 50 DEG C below zero and being stable in performance and excellent in cycle indicators.

Description

technical field [0001] The invention belongs to the technical field of lithium-ion batteries, and in particular relates to an electrolysis method for a novel lithium-ion battery discharged at ultra-low temperature Background technique [0002] As the marketization of lithium-ion batteries continues to deepen, people's expectations for battery performance are getting higher and higher. At present, it is difficult for commercialized lithium-ion batteries to meet the needs of important fields such as electric vehicles, aerospace technology, and military affairs. One of the main reasons is that the performance of batteries is not good at high and low temperatures. A broadening of the working temperature agenda is the focus of lithium-ion batteries. key issues. [0003] It has been proved to be a feasible technical approach to improve the temperature performance by starting with the electrolyte, because as an ion conductor that plays a role in the battery, the performance of the...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/0569
CPCH01M10/0567H01M10/0569H01M2300/0005H01M2300/0008Y02E60/10
Inventor 吕秀夯闫晓宾
Owner HUARUI XINXIANG CHEM
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