The invention discloses a modified 
epoxy resin composite material of a prereacted material of 
epoxy-terminated 
silicone oil and a preparation method and application thereof. The modified 
epoxy resin composite material of the prereacted material of the epoxy-terminated 
silicone oil contains 0.1-100 parts of prereacted material of the epoxy-terminated 
silicone oil, 100 parts of epoxy resin, 0-50 parts of silica and 5-70 parts of curing agent, wherein the 
structural formula of the prereacted material of the epoxy-terminated 
silicone oil is shown as the formula (1). Since the prereacted material of the epoxy-terminated 
silicone oil has a functional group capable of reacting with the epoxy resin, the polarity of the epoxy resin is enlarged and the compatibility becomes good, and thereby, the epoxy resin is better modified, which more evenly distributes the epoxy-terminated 
silicone oil in the epoxy resin, achieves smaller the dimensions of phase regions, and improves and the 
toughness and the 
heat stability of the epoxy resin, and thereby, the obtained modified 
epoxy resin composite material of the prereacted material of the epoxy-terminated silicone oil has wide application range and can be used as high-performance materials of dopes, structural adhesives, electronic 
package materials and the like.