836results about "Group 1/11 organic compounds without C-metal linkages" patented technology

Disclosed are metal organic frameworks that adsorb nitric oxide, NO-loaded metal organic frameworks, methods of preparing the NO-loaded metal organic frameworks, methods of releasing the nitric oxide into a solution or into air, and uses of the metal organic frameworks.

The invention discloses a near-infrared silver sulphide quantum dot as well as a preparation method and application thereof. The silver sulphide quantum dot has a monoclinic phase structure, the particle diameter of the silver sulphide quantum dot is below 8nm, and the surface of the silver sulphide quantum dot can be connected and modified with a hydrophilic group of hydrophilic reagent containing sulfydryl. The preparation method comprises the following steps: fully reacting a mixed reaction system containing silver source and long-chain mercaptan in a sealed environment; cooling the mixed reaction system, and then adding a polar solvent; carrying out centrifugation and wshing to obtain a hydrophobic near-infrared silver sulphide quantum dot; fully mixing the hydrophobic near-infrared silver sulphide quantum dot and hydrophilic reagent containing sulfydryl in organic solvent to react; and carrying out centrifugation and washing the reacting mixture to obtain the biocompatibility near-infrared silver sulphide quantum dot. The quantum dot disclosed by the invention has the advantages of high fluorescence yield, good fluorescence stability, good biocompatibility and even size, and can be used for biological tissue imaging; and the preparation technology has moderate condition, short period and good repeatability, is simple to operate and is easy to control.

The present invention relates to a silver complex obtained by reacting at least one silver compound represented by the formula 2 below with at least one ammonium carbamate compound or ammonium carbonate compound represented by the formula 3, 4 or 5 below:

The invention relates to a MOF (metal organic framework)-modified materials and methods of making and methods of using same. The MOFs are covalently bound to the materials. Examples of suitable materials include fibers and thin films. The MOF-modified materials can be made by forming MOFs in situ such that they are covalently bound to the materials. The MOF-modified materials can be used in methods where gases and / or toxic chemicals are absorbed.

A method is disclosed for the formation of metal chelates which are able to remain stable in high alkaline environments when compared to metal chelates produced from a reaction with amino acids. The method involves the reaction of sugars, amino groups, and metal components for a sufficient period of time and temperature in a water solution. Additionally, the stability of metal chelates can be enhanced by oxidation of the sugars with an oxidizing agent such as hydrogen peroxide which form an MRP which will react with the metal component to form a more stable metal chelate than if oxidation were not utilized.

Metal ketoiminate or diiminate complexes, containing copper, silver, gold, cobalt, ruthenium, rhodium, platinum, palladium, nickel, osmium, or indium, and methods for making and using same are described herein. In certain embodiments, the metal complexes described herein may be used as precursors to deposit metal and metal-containing films on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.

The present invention relates to sorbants such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), porous aromatic frameworks (PAFs) or porous polymer networks (PPNs) for separations of gases or liquids, gas storage, cooling, and heating applications, including, but not limited to, adsorption chillers.

There is provided a metal-containing azo compound suitably used for an recording layer of an optical medium, which is represented by at least one of the following general formulae:wherein M(II) is a bivalent metal, X1 and X2 are each a residue that forms a monocyclic or polycyclic aromatic ring, Y1 and Y2 are each a residue that forms a nitrogen-containing aromatic heterocycle, and one residue is different from the other in at least one of a combination of X1 and X2, and a combination of Y1 and Y2; and there is also provided an optical recording medium of which recording layer comprises said metal-containing azo compound.

Processes for producing carboxylic acid-stabilized silver nanoparticles are disclosed. The processes comprise (a) forming a suspension of silver salt particles in a carboxylic acid; (b) forming a solution of an organohydrazine and a first organic solvent; (c) heating the suspension; (d) adding the solution to the suspension to form a mixture; and (e) reacting the mixture to form carboxylic acid-stabilized silver nanoparticles.

The purpose of the invention is providing a micro-channel chemical preparation method of porous metal-organic framework material. The method comprises the following steps: respectively injecting a liquid medium containing one or more organic compounds with at least one unidentate ligand, a liquid medium containing one or more metal ions, a liquid medium containing a deprotonation assistant and an inert gas into a micro-channel reactor through different inlets, carrying out a coordination reaction on the above obtained mixed material liquid in the micro-channel at a certain temperature under a certain pressure to form a coordination compound, crystallizing, filtering, washing, and drying to prepare the porous metal-organic framework material, wherein the micro-channel reactor has at least two inlets and one outlet; the addition amount of the deprotonation assistant is 0-50% of the mole number of all metal ions; a ratio of the volume velocity of inert gas added into the micro-channel reactor to the bulk volume velocity of the liquid phase is 0-100:1; and the crystallization process can be omitted. The method has the characteristics of simple and safe operation, high efficiency, large throughput and easy amplification.

The invention discloses a baicalin metal complex of which the molecular formula is (C21H17O11) xM (H2O) y, wherein M in the formula is Cu (II), x is 1 and y is 2; or M is Fe (III), x is 2 and y is 0; or M is La (III) or Y (III), x is 3 and y is 0. The preparation method comprises the following steps: adding aqueous alkali into baicalin until the baicalin and alkali (sodium bicarbonate, potassium bicarbonate, sodium formate, potassium formate, sodium acetate, potassium acetate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, sodium phosphate or potassium phosphate) are just completely reacted, then adding metal salt (copper salt, ferric salt, lanthanum salt or yttrium salt) for reaction to obtain the baicalin metal complex. The baicalin metal complex has obviously stronger antibacterial and antitumor activities than the baicalin, can be used for preparing antibacterial drugs and antitumor drugs, and has good development and application prospects. In the preparation method, an organic solvent is not used, a strong basic condition is not adopted, and the method is simple and feasible, is green and environment-friendly and has the advantages of low cost, high product purity and high yield.

Copper (I) amidinate precursors for forming copper thin films in the manufacture of semiconductor devices, and a method of depositing the copper (I) amidinate precursors on substrates using chemical vapor deposition or atomic layer deposition processes.

The present invention relates to compositions for forming reflecting layer having organic silver complexes, and method for preparing reflecting layer using the same. More specifically, it relates to compositions for forming reflecting layer including silver complexes that have distinct structures and the method for preparing reflecting layer, where primary coating is applied to promote the adhesive force to materials such as plastic, ceramic, metal, etc. and then a high-reflecting layer is formed by using the silver coating fluid, followed by transparent coating for protection.

Metal-organic framework-based molecular sieves comprising pores with a temperature-adjustable pore opening. The temperature-adjustable pore size molecular sieves comprise a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a functionalized hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are held in proximity with each other to form at least one hydrophobic chamber. The hydrophobic moieties form temperature-adjustable pore size hydrophobic pores. When adjusted to a pre-selected temperature the temperature-adjustable pore openings allow for the passage of molecules having a size less than the size of the pre-selected temperature-adjustable pore opening.

Metal ketoiminate or diiminate complexes, containing copper, silver, gold, cobalt, ruthenium, rhodium, platinum, palladium, nickel, osmium, or indium, and methods for making and using same are described herein. In certain embodiments, the metal complexes described herein may be used as precursors to deposit metal and metal-containing films on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.

Metal complexes, containing copper, silver, gold, cobalt, ruthenium, rhodium, platinum, palladium, nickel, osmium, and / or indium, and methods for making and using same are described herein. In certain embodiments, the metal complexes described herein may be used as precursors to deposit metal or metal-containing films on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.

Copper (I) amidinate precursors for forming copper thin films in the manufacture of semiconductor devices, and a method of depositing the copper (I) amidinate precursors on substrates using chemical vapor deposition or atomic layer deposition processes.

The present invention provides homoleptic and heteroleptic copper(I) complexes having sterically demanding ligands, such as the bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I) complex and related complexes, methods of synthesis of these complexes and uses thereof. These copper(I) complexes are useful for various applications including photovoltaic cells, light-emitting electrochemical cells, and analyte sensor systems.

A process for the preparation of a dry crystalline metal organic framework which comprises: a) spray drying at least one metal ion and at least one organic ligand which is at least bidentate into a spray dryer in the presence of a solvent, wherein the reaction of the at least one metal ion with the at least one organic ligand to yield the metal organic framework and the drying of the obtained metal organic framework take place simultaneously inside the spray dryer, and b) collecting the formed dry crystalline metal organic framework.

The present invention relates to a silver complex obtained by reacting at least one silver compound represented by the formula 2 below with at least one ammonium carbamate compound or ammonium carbonate compound represented by the formula 3, 4 or 5 below:

This invention relates to methods for materials using compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. This invention further relates to thin film CA(I,G,A)S, CAIGAS, A(I,G,A)S, AIGAS, C(I,G,A)S, and CIGAS materials made by a process of providing one or more polymeric precursor compounds or inks thereof, providing a substrate, depositing the compounds or inks onto the substrate; and heating the substrate at a temperature of from about 20° C. to about 650° C.

The present invention generally relates to supramolecular assemblies and their modes of synthesis. The supramolecular assemblies include a 1:8 ratio of a supermolecular polyhedral building block and a triangular molecular building block, the supermolecular polyhedral building block having points of extension corresponding to the vertices of a rhombicuboctahedron for linking the supermolecular polyhedral building block to the triangular building block.

This invention relates to processes for compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. In particular, this invention relates to molecular precursor compounds and precursor materials for preparing photovoltaic layers including CAIGAS.

The invention relates to a metal-organic framework crystalline material with a nano-cage structure, in particular to a polyoxometalate (POM)-based metal-organic frameworks (POMOFs) crystalline material with a nano-cage structure and a preparation method and application thereof and aims to solve the problems in the prior art that a POMOFs crystalline material with a nano-cage structure is high in synthesis difficulty and poor in rhodamine B organic dye degradation effect. The POMOFs crystalline material has the chemical formula of Ag10(tta)4(H2O)4(SiW<IV>10W<V>2O40), the tetragonal system, and the space groups of I-4m2, alpha=90, beta=90, gamma=90 and Z=2. The preparation method comprises the following steps: dissolving silicotungstic acid, silver nitrate, tetrazole and a mineralizer in distilled water; regulating the pH value; carrying out a reaction for 3 days at 160 DEG C. The POMOFs crystalline material with the nano-cage structure can be obtained.

There is provided a light-emitting material comprising a metal coordination compound having a partial structure represented by the following general formula (1). The light-emitting material has high luminous efficiency and high stability and can be produced at a low cost.

The present invention relates to new silver-ion super-complex compositions. More particularly, the present invention describes silver-ion super-complex compositions comprising a silver-thiosulfate ion complex further complex with a primary, secondary or tertiary amine. These silver-ion super-complex compositions are stable in a saline environment and have improved solvent miscibility.

Small organometallic probes comprise a core of metal atoms bonded to organic moieties. The metal atoms are gold, silver, platinum, palladium, or combinations thereof. In one embodiment, a multifunctional organometallic probe comprises a core of metal atoms surrounded by a shell of organic moieties covalently attached to the metal atoms, a fluorescent molecule, e.g., fluorescein, covalently attached to one of the organic moieties, and a targeting molecule, e.g., an antibody, covalently attached to another of the organic moieties.

The present invention relates to novel copper formate complexes and the deposition of metallic copper on substrates or in or on porous solids using these novel copper complexes.

A bipyridine-based metal complex includes a complex of bipyridine-based ligands and metals, and is utilized in an ink composition. The bipyridine-based metal complex may be used alone, as well as in combination with other coloring agents.