Na-rich 
electrolyte compositions provided herein can be used in a variety of devices, such as 
sodium ionic batteries, capacitors and other electrochemical devices. Na-rich 
electrolyte compositions provided herein can have a 
chemical formula of Na3OX, Na3SX, Na (3-δ) Mδ / 2OX and Na (3-δ) Mδ / 2SX wherein 0<δ<0.8, wherein X is a monovalent anion selected from 
fluoride, 
chloride, 
bromide, 
iodide, H−, CN−, BF4−, BH4−, ClO4−, CH3−, NO2−, NH2− and mixtures thereof, and wherein M is a 
divalent metal selected from the group consisting of 
magnesium, 
calcium, 
barium, 
strontium and mixtures thereof. Na-rich 
electrolyte compositions provided herein can have a 
chemical formula of Na (3-δ) Mδ / 3OX and / or Na (3-δ) Mδ / 3SX; wherein 0<δ<0.5, wherein M is a trivalent cation M3, and wherein X is selected from 
fluoride, 
chloride, 
bromide, 
iodide, H−, CN−, BF4−, BH4−, ClO4−, CH3−, NO2−, NH2− and mixtures thereof. Synthesis and 
processing methods of NaRAP compositions for battery, 
capacitor, and other electrochemical applications are also provided.