30results about How to "Enhanced stone chip resistance" patented technology

The invention discloses a two-component polyurethane coating used for an automobile and a preparation method thereof. The coating comprises two components, namely a component A and a component B, and hydroxy acrylic resin in the component A and aliphatic series polyisocyanates in the component B are taken as the basic components, The preparation method comprises the following steps: adding linear saturated polyester, solvent, auxiliaries and color padding into the basic components, wherein the weight ratio of the component A to the component B is (2.5-5.5):1, the component A comprises hydroxide radical, the linear saturated polyester, wetting dispersing agent, catalyst, coloringpigment, padding, rust resisting pigment and solvent, and the component B comprises the aliphatic series polyisocyanates and solvent. The coating provided by the invention can be used for improving the glossiness of an under-coat coating, the adhesion between the layers of the under-coat coating and antirust primer, the weather fastness and stone-impact resistance of a solidified coating film, and the shock resistance and water resistance of the solidified coating film at the same time.

The invention discloses an integrated-form water-cooling power battery shell used for new energy automobiles. The integrated-form water-cooling power battery shell used for new energy automobiles comprises an upper shell body and a lower shell body; the lower shell body is composed of a bottom plate and a side plate; the bottom plate is a cuboid, and is of a double layer structure composed of an upper layer bottom plate and a lower layer bottom plate; vertical ribs are uniformly arranged between the upper layer bottom plate and the lower layer bottom plate; a plurality of cooling water runnersare arranged between the upper layer bottom plate and the lower layer bottom plate; the cooling water runners are arranged to be parallel to the width direction of the bottom plate; the side plate isa rectangle frame composed of two long edge side plates and two short edge side plates; a water inlet channel and a water outlet channel are arranged on the external sides of the two long edge side plates respectively; one end of each cooling water runner is communicated with the water inlet channel, and the other end is communicated with the water outlet channel. According to the integrated-formwater-cooling power battery shell, a cooling device is arranged on the lower shell body via integration, so that the battery shell whole structure is simplified greatly, and the cost of the battery shell is reduced; the cooling water runners are arranged in the bottom plate of the lower shell body, so that the risk of module short circuit caused by water leakage of conventional cooling pipelinesis reduced; and the external walls of the cooling water runners are contacted with battery modules, so that cooling effect is improved.

A pneumatic tire is provided which can realize an increase in stone-catching resistance while suppressing uneven wear such as river wear in a tread portion. In a pneumatic tire in which a center rib and intermediate ribs which are defined by four straight-line main grooves, which extend continuously in a circumferential direction of the tire and shoulder ribs which are defined by the main grooves which are situated closer to shoulders of the tire and straight-line thin grooves which extend continuously in the circumferential direction of the tire in the vicinity of tread ground-contacting edges are formed on the surface of a tread of the tire, inclination angles of a shoulder side groove wall of the main groove which defines the shoulder rib and a tire's equator line side groove wall of the thin groove are both such an angle that the shoulder side groove wall and the tire's equator line side groove wall are inclined at an angle of not more than five degrees in a direction in which the width of a proximal portion of the rib is expanded relative to normal lines to the tread.

The invention provides a polyamide modified polyester resin having the following structure, wherein M represents -(R3-CO-NH-R4-NH-CO)n3-R3-. The invention also provides a preparation method of the polyester resin and an automotive primer surfacer containing the polyester resin. The strength and toughness of the polyester resin are enhanced by modifying saturated polyester resin by using polyamide polymer oligomer with terminal carboxyl groups, so that the saturated polyester resin having excellent mechanical properties used for coatings is obtained. The stone impact-resistant performance of paint films can be enhanced by using the polyester resin in the automotive primer surfacer.

The invention relates to a synthetic method of compound blocked polyisocyanates by using multiple sealants to compound and block terminal groups, which is characterized in that 300-600 parts of polyisocyanate ( by mass part, the same below), 50-350 parts of active methylene compound and 290-335 parts of solvent are stirred for 1-3 hours at a temperature of 50-90 DEG C; 50-350 parts of another active methylene compound is added to be stirred for 1-2 hours at a temperature of 50-90 DEG C; 20-130 parts of pyrazole derivative compound is added to be stirred at a temperature of 50-85 DEG C in batches until NCO groups can not be detected or NCO% is not higher than 0.2% (about 0.5-2 hours). Compared with the prior art, the invention has improved technology and obvious advantages.

The invention discloses self-phosphating waterborne polyurethane acrylate paint applied to a car axle coating production line and a preparation method thereof. The preparation method comprises the following steps: carrying out chain extension reaction on polyether glycol, diisocyanate, dimethylolpropionic acid and 1,4-butylene glycol to obtain an isocyanate-terminated waterborne polyurethane prepolymer; adding hydroxyethyl acrylate to carry out end-capping reaction, adding triethylamine to perform neutralizing and salifying after cooling, adding water for emulsifying, evaporating out a solvent to prepare a semi-transparent waterborne polyurethane macromonomer; adding acrylate monomer mixed liquor which is mixed with initiator potassium persulfate and contains acrylic phosphate for carrying out polymerization reaction to prepare the self-phosphating waterborne polyurethane acrylate emulsion. A paint dropped in a coating process of the self-phosphating waterborne polyurethane acrylate paint can be recycled, and can be self-phosphated to avoid a surface phosphating treatment process; moreover, the flexibility, compactness and flash erosion resistance of the cured coating can satisfy the coating performance of a car axle steel plate.

The invention provides a water-based stone-crash-resistant blocked polyisocyanate curing agent as well as a preparation method thereof and a water-based coating. The water-based stone-crash-resistantblocked polyisocyanate curing agent comprises the following raw materials: a polyisocyanate compound, a hydrophilic chain alcohol, a reactive methylene-based sealing agent, a cosolvent, an alkali metal salt of an alcohol and a neutralizing agent, wherein a molar amount of NCO in the polyisocyanate compound is greater than a molar amount of total active hydrogen. The invention also provides the preparation method of the water-based stone-crash-resistant blocked polyisocyanate curing agent and the water-based coating. According to the curing agent provided by the invention, a cross-linking density of a coating film can be improved, and therefore the stone crash resistance of the coating in automobiles under the low-film-thickness conditions can be improved.

The invention relates to the technical field of coating, in particular to a dual-component waterborne polyurethane intermediate coating composition with anti-sagging characteristics and a preparationmethod thereof. The composition is mainly prepared from an A component and a B component. The A component is prepared from, by mass, 28-45% of hydroxyl functionalized waterborne acrylic resin, 2-9% ofa cosolvent A, 0.2-1.2% of a dispersant, 0.2-0.35% of a leveling agent, 0.1-0.3% of a defoamer, 0.1-0.45% of a pH regulator, 6-17% of pigment, 14-40% of a filler, 4.5-12.5% of a waterborne anti-sagging polymer containing a polyurea group and 6.55-12% of deionized water. The composition has excellent sagging resistance, adhesive force, waterproofness and resistance to stone crash.

The invention relates to the technical field of coating, in particular to a baking type waterborne acrylic intermediate coating composition with anti-sagging characteristics and a preparation method thereof. The composition is mainly prepared from, by mass, 25-40% of hydroxyl functionalized waterborne acrylic resin, 2.2-3.1% of waterborne amino resin, 1.5-5.5% of a cosolvent A, 0.2-0.9% of a dispersant, 0.1-0.35% of a leveling agent, 0.05-0.2% of a defoamer, 0.02-0.1% of a pH regulator, 6-29% of pigment, 20-40% of a filler, 3.5-15% of a waterborne anti-sagging polymer containing a polyurea group and 5.83-10.45% of deionized water. The composition has excellent sagging resistance, adhesive force, waterproofness and resistance to stone crash.

The invention provides a graphene oxide waterborne polyurethane stone-chip-resistant anti-corrosion coating and a preparation method thereof. The coating comprises an aliphatic or alicyclic isocyanatemonomer, a polyhydric alcohol, a catalyst, a hydrophilic chain extender, a crosslinking agent, a silane coupling agent, a graphene oxide aqueous solution and a first neutralizing reagent. The preparation process of the anti-corrosion coating is simple and easy to operate, has a low equipment requirement and a short curing time, can effectively reduce the protection cost, and is suitable for industrial production.

The invention discloses an oil metallic paint used for commercial vehicle surface coating. The oil metallic paint comprises, by weight, 28 to 40 parts of acrylic resin, 20 to 30 parts of polyester resin, 30 to 60 parts of a paint naphtha,20 to 28 parts of tung oil, 15 to 22 parts of isopropanol, 6 to 12 parts of water, 3 to 6 parts of zinc molybdate, 5 to 10 parts of an aluminium powder pigment, 50 to 80 parts of a grinding auxiliary agent, and 4 to 8 parts of a processing auxiliary agent. The oil metallic paint used on commercial vehicle surfaces is simple in preparation method, is low in preparation cost, is safe, is friendly to the environment, possesses excellent corrosion resistance, rusting resistance, weatherability, wear resistance, and shock resistance, is used for commercial vehicle surface coating, is convenient to use, is rapid in curing; no toxic substance is generation in preparation and using process; obtained coating film is flat and compact, is capable of improving vehicle surface coating film appearance effect and stone crash protection performance; and the oil metallic paint is worthy of popularization.

The invention aims to provide a sandwich structure bottom plate of a power battery lower box body and the power battery lower box body. The sandwich structure bottom plate comprises a water cooling system (3.4), a steel stamping lower bottom plate (3.6) and a carbon fiber plate (3.1) which are arranged in a layered manner from top to bottom, the water cooling system (3.4) comprises at least one water cooling plate, hanging lug through holes (3.4.9) are distributed in the water cooling plate, pressing rivet nuts (3.3) are distributed on the stamping lower bottom plate (3.6), water cooling platefixing bolts (3.5) penetrate through the hanging lug through holes (3.4.9) to be connected with the pressing rivet nuts (3.3) so as to fix the water cooling plate to the stamping lower bottom plate (3.6); the carbon fiber plate (3.1) is fixed on the stamping lower bottom plate (3.6) in a manner of adhesive connection; and bottom plate fastening bolts (3.2) used for external connection are distributed on the stamping lower bottom plate (3.6). Corrosion resistance and stone impact resistance of the bottom of the box body can be improved, the maintenance is convenient, the mechanical performanceis good while light weight is achieved, and the structural rigidity is high.

The invention provides cathode electrophoretic paint for a plate spring and a preparation method of the cathode electrophoretic paint. The cathode electrophoretic paint comprises epoxy resin; when the epoxy value of the epoxy resin is smaller than 0.4, the cathode electrophoretic paint further comprises epoxy diluent; on the contrary, the cathode electrophoretic paint further comprises a chain extender; and the epoxy diluent and the chain extender are flexible chain compounds. According to the epoxy value of the epoxy resin, the epoxy diluent or the chain extender of the flexible chain compound is added in the raw materials, the brittleness of the cathode electrophoretic paint is reduced, then stone crash resistance is improved, and meanwhile, salt fog resistance is improved.

The invention discloses a water-based metallic paint used for commercial vehicle surface coating. The water-based metallic paint comprises, by weight, 25 to 35 parts of aqueous polyester resin, 20 to32 parts of aqueous acrylic resin, 4 to 8 parts of zinc dihydrogen phosphate, 2 to 3 parts of nanometer titanium dioxide, 3 to 8 parts of an oxidizing agent, 5 to 12 parts of a sodium hydroxide solution, 4 to 8 parts of methanol, 3 to 8 part of an aluminium powder pigment, 2 to 5 parts of an environmental protection inorganic pigment, 2 to 4 parts of a processing auxiliary agent, and 50 to 80 parts of water. The raw materials of the water-based metallic paint are safe, are friendly to the environment, and are cheap; the aluminium powder pigment is subjected to pretreatment and oxidation modification, so that the stability and the dispersion performance of the aluminium powder pigment in water are improved. The water-based metallic paint is simple in preparation method, is low in preparation cost, possesses excellent corrosion resistance, wear resistance, weatherability, rusting resistance, antibacterial performance, shock resistance, and ultraviolet resistance, is used for commercial vehicle surface coating, is convenient to use, is rapid in curing; beautifying effect is excellent;and the water-based metallic paint is worthy of popularization.

The invention relates to a synthetic method of compound blocked polyisocyanates by using multiple sealants to compound and block terminal groups, which is characterized in that 300-600 parts of polyisocyanate ( by mass part, the same below), 50-350 parts of active methylene compound and 290-335 parts of solvent are stirred for 1-3 hours at a temperature of 50-90 DEG C; 50-350 parts of another active methylene compound is added to be stirred for 1-2 hours at a temperature of 50-90 DEG C; 20-130 parts of pyrazole derivative compound is added to be stirred at a temperature of 50-85 DEG C in batches until NCO groups can not be detected or NCO% is not higher than 0.2% (about 0.5-2 hours). Compared with the prior art, the invention has improved technology and obvious advantages.

The invention discloses an automobile chassis protective agent and a preparation method thereof. The automobile chassis protective agent comprises the following raw materials in parts by weight: 90-100 parts of paraffin, 20-30 parts of microcrystalline wax, 3-6 parts of polyethylene wax, 2-4 parts of modified montmorillonite, 6-8 parts of polyurethane acrylate resin, 2-3 parts of a sulfonate type antirust agent, 1-2 parts of a calcium salt type antirust agent, 2-3 parts of a nonionic antirust agent and 3-4 parts of a phenolic antioxidant. The modified montmorillonite is obtained by modifying Na-montmorillonite by adopting CTAB. The automobile chassis protective agent is good in stability, has good adhesive force with the automobile chassis, and has excellent high and low temperature adaptability, anti-rust performance and wear resistance.

The invention discloses waterborne polyurethane-polyacrylate resin, which is mainly obtained by reaction of a waterborne polyurethane prepolymer, an acrylic monomer and an initiator, wherein the waterborne polyurethane prepolymer is obtained by reacting a polyol prepolymer, an isocyanate monomer, a solvent, a hydrophilic monomer, a functional monomer, a catalyst, a chain extender, an acrylic monomer and an organic base. The waterborne polyurethane polyacrylate resin has extremely low VOC content and is green and environment-friendly, and meanwhile, waterborne metal flashing paint prepared fromthe waterborne polyurethane polyacrylate resin has excellent stone chip resistance after film formation.

The invention relates to a water-based blocked isocyanate curing agent, a preparation method thereof, and a water-based paint. The water-based blocked isocyanate curing agent includes the following raw materials: polyisocyanate trimer, polyethylene glycol monomethyl ether, polyether glycol, blocking agent, cosolvent, alkali metal alkoxide and neutralizing agent; wherein, the The polyisocyanate is selected from at least one of aliphatic polyisocyanate trimer and aromatic polyisocyanate trimer, and the polyethylene glycol monomethyl ether is selected from polyethylene glycol ether monohydric alcohols with a molecular weight of 300-2000 The molecular weight of the polyether diol is 120-1000. The water-based blocked isocyanate curing agent can react with resins with active groups such as amino resins and polyester resins in coating formulations, and introduce a large number of flexible segment structures into the coating film, which can delay the energy release of the coating film when it is hit by stones , and then improve the anti-stone chip performance of the coating film, so that the coating film has stone chip resistance under the condition of low film thickness.

The invention relates to the technical field of coating, in particular to a dual-component waterborne polyurethane intermediate coating composition with anti-sagging characteristics and a preparationmethod thereof. The composition is mainly prepared from an A component and a B component. The A component is prepared from, by mass, 28-45% of hydroxyl functionalized waterborne acrylic resin, 2-9% ofa cosolvent A, 0.2-1.2% of a dispersant, 0.2-0.35% of a leveling agent, 0.1-0.3% of a defoamer, 0.1-0.45% of a pH regulator, 6-17% of pigment, 14-40% of a filler, 4.5-12.5% of a waterborne anti-sagging polymer containing a polyurea group and 6.55-12% of deionized water. The composition has excellent sagging resistance, adhesive force, waterproofness and resistance to stone crash.

The invention relates to the technical field of coatings, specifically to a baking type waterborne acrylic coating composition with excellent thixotropy and a preparation method thereof. The coating composition provided by the invention is prepared from the following main raw materials by weight: 0.05 to 0.45% of a functional filling material A, 10 to 15% of deionized water, 30 to 38% of tertiaryamine group containing hydroxyl-functionalized waterborne acrylic resin, 2.5 to 4.5% of waterborne amino resin, 4.5 to 8% of a cosolvent A, 0.1 to 0.8% of a dispersant, 0.1 to 0.55% of a leveling agent, 0.1 to 0.65% of an anti-foaming agent, 0.05 to 0.4% of a pH regulator, 5 to 15% of a pigment, 10 to 40% of a filling material B, 0.1 to 0.85% of a rheological auxiliary agent and 3.5 to 9.7% of a cosolvent B, wherein the functional filling material A is hectorite or flaky silicate. The coating provided by the invention has excellent thixotropy, sag resistance and stone-bumping resistance.

The invention discloses a bicomponent polyurethane coating, which comprises a component A and a component B. The component A comprises a hydroxy acrylic acid resin, a filler, an auxiliary agent, a solvent, and linear saturated polyester, and the component B comprises an isocyanate curing agent, a solvent, a water absorber (containing or not containing) and a drier (containing or not containing), wherein a hydroxyl value of the linear saturated polyester is between 20 and 36mgKOH / g, and an acid value is between 10 and 30mgKOH / g. The bicomponent polyurethane coating is particularly applicable to a middle coating for the coating of the surfaces of automobiles, further solves the problem of inter-layer adhesion of the middle coating and an anti-corrosive primer and a finishing coat, and strengthens the stone chip resistance and the shock resistance of coatings at the same time.

The invention relates to an aqueous blocked isocyanate curing agent, a preparation method therefor and an aqueous coating material. The aqueous blocked isocyanate curing agent comprises the followingraw materials: a polyisocyanate trimer, methoxy polyethylene glycol, polyether diol, a blocking agent, a cosolvent, alkali metal alkoxide and a neutralizer, wherein the polyisocyanate is at least oneselected from an aliphatic polyisocyanate trimer and an aromatic polyisocyanate trimer, the methoxy polyethylene glycol is one selected from polyglycol ether monoalcohols with the molecular weight of300 to 2,000, and the polyether diol has the molecular weight of 120 to 1,000. The aqueous blocked isocyanate curing agent can react with resin with active groups such as amino resin and polyester resin in a coating formula, a large number of soft segment structures are introduced into a coating film, the energy release of the coating film during stone impact stressing can be retarded, and then, the stone impact resistance of the coating film is improved, so that the coating film can have stone impact resistance under the condition of low film thickness.

The invention discloses a preparation method of a waterborne polyacrylate emulsion and belongs to the field of coatings. The preparation method comprises the steps: grafting a glycolide molecule on anacrylic monomer by a glycolide ring opening addition reaction to prepare a polyglycollide-modified acrylate monomer oligomer; then, adding deionized water and an emulsifying agent into the oligomer;adding an initiator solution for an emulsion polymerization reaction; and then preparing the waterborne polyacrylate emulsion. The preparation process is simple, conditions are easy to control, the prepared waterborne polyacrylate emulsion is good in storage stability and can have a wide application prospect in the field such as plastics and rubber, and a coating of the waterborne polyacrylate emulsion has excellent adhesion, impact resistance and stone crash resistance.

The invention provides a polyamide modified polyester resin having the following structure, wherein M represents -(R3-CO-NH-R4-NH-CO)n3-R3-. The invention also provides a preparation method of the polyester resin and an automotive primer surfacer containing the polyester resin. The strength and toughness of the polyester resin are enhanced by modifying saturated polyester resin by using polyamide polymer oligomer with terminal carboxyl groups, so that the saturated polyester resin having excellent mechanical properties used for coatings is obtained. The stone impact-resistant performance of paint films can be enhanced by using the polyester resin in the automotive primer surfacer.

The invention discloses a filling pipe with a leakage alarm function, which includes a filler tube body and a filler port, A fuel hose is fixed at the tail end of the fuel pipe body, an electroplatedcolored zinc layer is arranged on the outer surface of the fuel pipe body, a PE powder layer is sprayed on the electroplated colored zinc layer, and a vent pipe and a return pipe are connected on thefuel inlet, and the vent pipe and the return pipe are fixed beside the fuel pipe body along the direction of the fuel pipe body; A mounting bracket is arranged on the filling port, and a DMTL leak detection valve is fixed on the mounting bracket. The invention has a simple structure, has colored zinc plating layer and PE powder layer arranged on the outer surface of the oil filling pipe body whichcan improve the corrosion resistance and stone impact resistance of the oil filling pipe, and furthermore, the safety of the oil filling pipe is improved through the setting of the DMTL leakage detection valve.

The invention relates to the technical field of coating, in particular to a baking type waterborne acrylic intermediate coating composition with anti-sagging characteristics and a preparation method thereof. The composition is mainly prepared from, by mass, 25-40% of hydroxyl functionalized waterborne acrylic resin, 2.2-3.1% of waterborne amino resin, 1.5-5.5% of a cosolvent A, 0.2-0.9% of a dispersant, 0.1-0.35% of a leveling agent, 0.05-0.2% of a defoamer, 0.02-0.1% of a pH regulator, 6-29% of pigment, 20-40% of a filler, 3.5-15% of a waterborne anti-sagging polymer containing a polyurea group and 5.83-10.45% of deionized water. The composition has excellent sagging resistance, adhesive force, waterproofness and resistance to stone crash.

The invention discloses self-phosphating waterborne polyurethane acrylate paint applied to a car axle coating production line and a preparation method thereof. The preparation method comprises the following steps: carrying out chain extension reaction on polyether glycol, diisocyanate, dimethylolpropionic acid and 1,4-butylene glycol to obtain an isocyanate-terminated waterborne polyurethane prepolymer; adding hydroxyethyl acrylate to carry out end-capping reaction, adding triethylamine to perform neutralizing and salifying after cooling, adding water for emulsifying, evaporating out a solvent to prepare a semi-transparent waterborne polyurethane macromonomer; adding acrylate monomer mixed liquor which is mixed with initiator potassium persulfate and contains acrylic phosphate for carrying out polymerization reaction to prepare the self-phosphating waterborne polyurethane acrylate emulsion. A paint dropped in a coating process of the self-phosphating waterborne polyurethane acrylate paint can be recycled, and can be self-phosphated to avoid a surface phosphating treatment process; moreover, the flexibility, compactness and flash erosion resistance of the cured coating can satisfy the coating performance of a car axle steel plate.

The invention provides cathode electrophoretic paint for a plate spring and a preparation method of the cathode electrophoretic paint. The cathode electrophoretic paint comprises epoxy resin; when the epoxy value of the epoxy resin is smaller than 0.4, the cathode electrophoretic paint further comprises epoxy diluent; on the contrary, the cathode electrophoretic paint further comprises a chain extender; and the epoxy diluent and the chain extender are flexible chain compounds. According to the epoxy value of the epoxy resin, the epoxy diluent or the chain extender of the flexible chain compound is added in the raw materials, the brittleness of the cathode electrophoretic paint is reduced, then stone crash resistance is improved, and meanwhile, salt fog resistance is improved.