The invention provides a preparing method of an environment-friendly 
solvent-type electrostatic 
spinning waterproof and 
moisture-permeable membrane. The preparing method is characterized by comprisingthe steps of 1, preparing a high-molecular 
polymer solution with water or environment-friendly alcohols being solvents, adding a corresponding water-soluble or 
alcohol-soluble water repelling agent and cross-linking agent, and preparing a hydrophobic 
fiber membrane through an electrostatic 
spinning technology; 2, conducting aftertreatment on the 
fiber membrane to trigger a chemical crosslinking reaction between a 
polymer matrix and the cross-linking agent, reinforcing the 
water resistance of the 
fiber membrane and regulating the pore structure of the fiber membrane to obtain the environment-friendly 
solvent-type electrostatic 
spinning waterproof and 
moisture-permeable membrane. In the production process, no 
waste gas, waste water and 
solid waste are generated, the environment cannot be damaged, the prepared waterproof and 
moisture-permeable membrane does not contain toxic solvents, and in the actual application, the healthy of a wearer cannot be damaged; the resistance to 
water pressure of the fiber-based waterproof and moisture-permeable membrane is larger than or equal to 150 kPa, the 
moisture permeability is larger than or equal to 15,000 g / m<2> / d, the tensile breaking strengthis larger than or equal to 30 MPa, and the environment-friendly 
solvent-type electrostatic spinning waterproof and moisture-permeable membrane has a large application prospect in the field of functional protective clothes.