The invention discloses a 
processing method of an electronegative multilayer OPC drum. The 
processing method comprises the following steps that S1, a dispersing agent, an anti-
settling agent and 
titanium dioxide are taken, a mixture containing one or more of phenolic resin, 
acrylic resin and nylon resin is added to an 
alcohol solution, and a charge 
blocking layer material solution is prepared; S2,a charge generating layer material solution and a charge transmission layer material solution are prepared; S3, pretreatment is carried out on a pixel 
pipe, and successively the surface of the pixelpipe is subjected to 
coating in sequence, so that a charge 
blocking layer, a charge generating layer and a charge transmission layer are sequentially formed on the surface of the pixel 
pipe from inside to outside; and S4, stepped baking is carried out on the pixel 
pipe, then the pixel pipe is taken out for aging, and the finished OPC drum is obtained. According to the 
processing method of the electronegative multilayer OPC drum, modification is carried out on the charge 
blocking layer material arranged on the OPC drum in a 
coating manner, and the thixotropic property of the material solution is improved, so that the good sagging property is achieved when the 
coating thickness is relatively thick, and the uniformity of the subsequent coating is guaranteed when the thickness of the charge blocking layer is increased.