The invention discloses a process for a 420-500 micron ultra-thick electrolytic 
copper foil. The process comprises the following steps of 1, unreeling; 2, activating; 3, 
pickling; 4, coarsening and curing; 5, carrying out 
barrier layer treatment; 6, carrying out anti-oxidation treatment; 7, carrying out organic treatment; and 8, 
drying and rolling. According to the process, the effect of radiatingheat generated by components outside a substrate can be achieved, so that the purpose of high-density 
interconnection of high-power electric appliances is achieved, the original 
power transmission forms such as cable wiring, 
metal plate bars and the like are replaced, the production efficiency is improved, and the labor-hour cost, the cost of cables and accessories, the cost of 
maintenance management and the like of wiring are reduced; the 
copper foil high-current substrate can effectively reduce the 
thermal load of a PCB and achieve quality homogenization, so that the reliability of a terminal complete 
machine product using the high-current PCB is further improved; and by adopting the high-current substrate to replace the original cable wiring form, the design freedom degree of the wiring can be improved, so that the 
miniaturization of the whole terminal product is achieved.