The invention discloses a preparation method of 
acrylic acid organic 
silicon soap-free copolymerization 
emulsion. Unsaturated monomers, organic 
silicon, a reactive emulsifier, an initiator and water are adopted as raw materials, temperature of a reaction kettle is controlled by virtue of core-shell 
polymerization and 
soap-free 
polymerization technologies, then treatment is carried out for removing residual monomers, and a neutralizing agent is added for 
neutralization, so that 
emulsion is obtained. By virtue of the 
soap-free 
polymerization technology, better water white resistance can be realized with less expensive organic 
silicon monomer, and water absorption of a paint film is reduced. By virtue of the core-shell polymerization technology, a core layer with high 
glass transition temperature and a shell layer with lower 
glass transition temperature are obtained, so that synthetic 
emulsion has lower film formation temperature under the condition that the average 
glass transition temperature is the same with a homopolymerization technology, usage amount of a coalescing agent is reduced, and influence of 
solvent volatilization on atmospheric environment is reduced. The 
acrylic acid organic silicon soap-free copolymerization emulsion product does not contain a free emulsifying agent, so that influence of the 
acrylic acid organic silicon soap-free copolymerization emulsion product on the environment is greatly reduced, and the acrylic acid organic silicon soap-free copolymerization emulsion product is 
environmentally friendly; and the acrylic acid organic silicon soap-free copolymerization emulsion has excellent 
weather resistance, 
water resistance and 
pollution resistance.