The invention belongs to the field of ceramics, and particularly relates to a preparation method of a high-quality 
ceramic flat plate, which comprises the following steps: adding POSS (Polyhedral Oligomeric 
Silsesquioxane) into 
hydrochloric acid, carrying out ultrasonic treatment for 20-30 minutes, taking out a precipitate, putting the precipitate into a 
sodium hydroxide solution, carrying out 
microwave treatment for 1-2 hours, taking out, washing and 
drying to obtain hydroxylated POSS; the preparation method comprises the following steps: adding aluminum isopropoxide into 
ethanol, uniformly stirring to form a dissolving solution, putting hydroxylated POSS into the dissolving solution, carrying out low-temperature 
microwave treatment for 20-30 minutes, carrying out constant-
temperature treatment for 30-50 minutes to form a concentrated solution, taking out the concentrated solution, naturally airing the concentrated solution, and carrying out heating treatment to obtain aluminoxyl modified POSS; carrying out ball milling on nano aluminum 
oxide, aluminoxyl modified POSS, 
methyl cellulose and an 
ethanol water solution, and carrying out constant-
temperature treatment for 20-30 minutes to obtain 
slurry; carrying out vacuum stirring and defoaming on the 
slurry, and then carrying out 
tape casting and preliminary 
sintering to obtain a 
ceramic green body; 
coating the surface of the 
ceramic green body with 
silicon-aluminum liquid, 
coating the surface with 
aluminum foil after 
drying, carrying out 
microwave treatment for 20-40 minutes, and cooling and standing to obtain a pretreated flat plate; and carrying out presintering treatment on the pretreated flat plate for 1-2 hours, and carrying out isostatic pressing treatment for 2-5 hours to obtain the high-quality ceramic flat plate.