The invention provides an aluminum-free active region 808nm high-power 
quantum-well 
laser with asymmetric structure. From the bottom to the top, the structure of the 
laser sequentially comprises a substrate, a buffer layer, an N-type lower limiting layer, a lower 
waveguide layer, a 
quantum-well layer, an upper 
waveguide layer, a potential barrier limiting layer, a P-type upper limiting layer, a 
transition layer and an 
ohmic contact layer, wherein, the upper 
waveguide layer and the lower waveguide layer are made of aluminum-free material 
Indium gallium phosphide, the 
quantum-well layer made of 
gallium indium arsenide phosphide material, the waveguide layer and the quantum-well layer form the aluminum-free active region, and one layer potential barrier limiting layer which is made of P-type aluminum 
gallium indium phosphide material and 50nm-150nm thick and has a 
band gap wider than that of the upper limiting layer is arranged between the upper limiting layer and the upper waveguide layer. The 
laser of the invention can increase the 
optical limiting factor of the P-type material region, reduce the optical leakage towards the P-type material region, reduce optical 
absorption loss of a current carrier at the highly doped area, and improve the work efficiency of the laser; the structure of the invention also improves the limiting effect of the active region on the carrier, reduce the leakage of the carrier and is favorable to the decrease of the 
threshold current.