A method for treating aluminum electrolytic waste 
cathode carbon blocks by an acid and alkali 
combination method is characterized by comprising the following steps: (1) aluminum electrolytic waste 
cathode is added to concentrated basic solution for reaction; a filtered 
solid phase is obtained by filtering and is added to concentrated acid for reaction; and carbon 
powder is obtained after 
filtration; (2) filtrates are mixed and dropwise added with the concentrated basic solution, the pH value thereof is adjusted to 9, the obtained mixture is kept standing and filtered to obtain 
cryolite; (3) the filtrate is added with saturated 
bleach solution, kept standing and filtered to obtain 
calcium fluoride; (4) the fourth filtrates is heated, evaporated and crystallized to obtain 
sodium chloride solid. With the purposes of waste utilization and 
environmental protection, the method successfully provides the process for treating aluminum electrolytic waste 
cathode by the acid and alkali method, which causes the waste cathode to not be the conventional waste and 
pollutant and to become artificial mineral resources. The method solves the problem of waste utilization in 
aluminum electrolysis industry, improves benefit, and improves the comprehensive level of the 
aluminum electrolysis industry of China.