298 results about "Carbon nanocomposite" patented technology

The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

The invention provides a manganese dioxide / carbon nanocomposite and a preparation method and application thereof. The preparation method comprises the following concrete steps: mixing an aqueous solution of permanganate, a carbon carrier and an aqueous solution of a divalent manganese salt; carrying out a reaction to produce a precipitate; and carrying out washing and drying so as to obtain the manganese dioxide / carbon nanocomposite. The preparation method has the advantages of easiness, rapidness, environment friendliness and easy realization of scale-up synthesis. The prepared manganese dioxide / carbon nanocomposite is applicable to a super-capacitor, a metal-air battery and a fuel battery.

The present teachings relate to the application of electrical impedance tomography (EIT) to demonstrate the multifunctionality of carbon nanocomposite thin films under various types of environmental stimuli. Carbon nanotube (CNT) thin films are fabricated by a layer-by-layer (LbL) technique or other techniques and mounted with electrodes along their boundaries. The response of the thin films to various stimuli determined by relying on electric current excitation and corresponding boundary potential measurements. The spatial conductivity variations are reconstructed based on a mathematical model for the EIT technique. Here, the ability of the EIT method to provide two-dimensional mapping of the conductivity of CNT thin films is validated by (1) electrically imaging intentional structural defects in the thin films and (2) mapping the film's response to various pH environments.

The invention relates to a nickel disulfide carbon nano composite material and a preparation method and an application thereof, wherein the composite material is formed by coating a nickel disulfide nanosheet with a carbon layer. The preparation method comprises the following steps of preparing a nickel hydroxide nanosheet precursor by a hydrothermal method, performing magnetic stirring and dispersing in deionized water to obtain a uniform dispersion liquid of the nickel hydroxide nanosheet precursor, adding a buffering agent tris(hydroxymethyl) aminomethane hydrochloride, and adjusting the pHvalue to be 8.5 by adopting an alkali solution with the pH value of 13, adding dopamine hydrochloride, and magnetically stirring at room temperature for in-situ polymerization, and carrying out washing and centrifugally drying to obtain a nickel hydroxide nanosheet precursor / polydopamine composite material, and carrying out heat treatment and vulcanization with sublimed sulfur powder in a tubularfurnace in nitrogen atmosphere at a certain temperature to obtain the composite material. The preparation process is simple, easy to operate, green and non-toxic and friendly in material preparationprocess; and the prepared nickel disulfide carbon nano composite material is stable in structure, uniform in morphology and high in dispersion. The obtained nickel disulfide carbon nano composite material can be an ideal electrode material of a high-performance lithium ion battery, a supercapacitor and other new energy devices.

The invention relates to the technical field of nonmetallic mineral finish machining and inorganic processing, in particular to an attapulgite / graphite phase carbon nitride composite material. The attapulgite / graphite phase carbon nitride composite material takes attapulgite as a carrier and takes graphite phase carbon nitride as an active ingredient; the mass ratio of the attapulgite to the graphite phase carbon nitride is 1: 1 to 1: 10. By compounding the graphite phase carbon nitride with the attapulgite, the foreign ions in the attapulgite enter the crystal lattices of the graphite phase carbon nitride to increase the defects and change the energy level; the silicon oxide in the attapulgite can possibly form a heterojunction structure with the graphite phase carbon nitride so as to promote the transfer of photo-generated electrons and avoid the self-compounding of the photo-generated electrons; through the concerted catalysis action between the carrier and the active ingredient, the catalytic activity of the composite material is strengthened to a great extent.

The invention discloses an ultra-thin, self-supporting, flexible and all-solid-state super capacitor and a manufacturing method of the ultra-thin, self-supporting, flexible and all-solid-state super capacitor. The super capacitor comprises a position electrode, a solid electrolyte and a negative electrode, wherein the solid electrolyte is located between the positive electrode and the negative electrode to separate the positive electrode and the negative electrode, and the solid electrolyte evenly permeates inside a porous structure of the positive electrode and a porous structure of the negative electrode. The positive electrode and the negative electrode are made of carbon nanometer materials or carbon nanometer composite materials, and the outer side of the positive electrode and the outer side of the positive electrode are not completely embedded by the solid electrolyte and can be used for collecting currents. The thickness of the super capacitor is within the range of 10 nanometers to 10 micrometers, the inner portion of the capacitor is provided with no diaphragm, the outer portion of the capacitor needs no metal current collecting electrode or encapsulation, self-supporting can be realized, and at the same time the capacitor has high specific capacitance, high power density, high energy density, long life and high stability. The super capacitor has the advantages of being superior in performance, simple in manufacturing technology, and capable of satisfying the development demands of flexible, miniature, light electronic products at the same time, and having wide application prospects.

The invention is directed in a first aspect to electron-conducting porous compositions comprising an organic polymer matrix doped with nitrogen atoms and having elemental sulfur dispersed therein, particularly such compositions having an ordered framework structure. The invention is also directed to composites of such S / N-doped electron-conducting porous aromatic framework (PAF) compositions, or composites of an S / N-doped mesoporous carbon composition, which includes the S / N-doped composition in admixture with a binder, and optionally, conductive carbon. The invention is further directed to cathodes for a lithium-sulfur battery in which such composites are incorporated.

The invention relates to the technical field of performance enhancing and functionalization of carbon nanocomposite materials, in particular to a polymer thermal conductive film containing uniformly dispersed and highly oriented graphene and a preparation method thereof. The thermal conductive film material is composed of the following components: a polymer matrix, graphene, second thermal conductive filler, a surface treatment agent, a filler coating agent and a processing aid. A technical route combining "high shear melting dispersion" and "high stretching" is employed to promote the uniformdispersion of graphene nanosheets and other thermal conductive filler in the polymer matrix and the acquisition of high orientation, graphene itself is utilized to construct a long-range continuous and three-dimensional hybrid thermal conductive network structure, thus overcoming the anisotropy of graphene, and constructing a stable and effective thermal conductive network.

The invention discloses a high specific capacity spindle-shaped ferroferric oxide / carbon nano composite material for a negative electrode of a lithium ion battery. A raw material, namely soluble ferric salt is solved in a mixed solvent of glycerol and distilled water; after low-temperature treatment, precipitates are collected, and a spindle-shaped iron oxide hydroxide (FeOOH) precursor is obtained; and after the precursor is subject to carbothermal reduction, the ferroferric oxide / carbon nano composite material with the same appearance is obtained. The invention discloses a preparation method of the spindle-shaped ferroferric oxide / carbon, which has the advantages that the operation is simple, convenient and simple to do, the used raw material has a cheap price, mass production is facilitated, and the synthetized spindle-shaped ferroferric oxide / carbon nano composite material shows high first time coulomb efficiency and high specific capacity when being used as the negative electrode of the lithium ion battery, and is a promising negative electrode material of the lithium ion battery.

The present invention relates to carbon nanocomposite sorbents. The present invention provides carbon nanocomposite sorbents, methods for making the same, and methods for separation of a pollutant from a gas that includes that pollutant. Various embodiments provide a method for reducing the mercury content of a mercury-containing gas.

The invention discloses a preparation method of a polymer foam-based multi-stage carbon nanocomposite pressure-sensitive material. The preparation method comprises the following specific steps: dispersing graphene oxide into deionized water, and performing ultrasonic dispersion to obtain a negatively charged aqueous graphene dispersion; performing a refluxing reaction on gamma-aminopropyltriethoxysilane in a toluene solvent protected by a nitrogen atmosphere to achieve surface aminosilane modification of hydroxylated carbon nanotubes, dispersing the aminosilane-modified carbon nanotubes into deionized water, and dropwise adding a hydrochloric acid solution for pH adjustment to obtain a positively charged aminosilane-modified aqueous carbon nanotube dispersion; immersing perforated polymerfoam into the aqueous graphene dispersion, repeatedly squeezing, taking out after saturation, and drying in a drying box to obtain a polymer foam-based graphene composite material; then immersing thepolymer foam-based graphene composite material into the aminosilane-modified aqueous carbon nanotube dispersion, gently squeezing repeatedly and then drying. By the preparation method, the obtained conductive composite foam material has good flexibility, resilience and pressure-sensitive response.

The present invention relates to composite electrodes for electrochemical devices, particularly to carbon nanotube composite electrodes for high performance electrochemical devices, such as ultracapacitors.

The invention discloses a porous carbon-coated ZnO nanocomposite material and a preparation method thereof. The present invention adopts a simple method of coating and calcining to synthesize porous carbon-coated ZnO nanocomposite material, and the preparation process is simple. First, 2-methylimidazole and ZnO nanoparticles are used as raw materials to construct ZnO heterostructure material, and then The obtained material is calcined to obtain a layer of porous carbon nanocomposite material supported on the ZnO surface. That is, the porous carbon-coated ZnO nanocomposite material is obtained; the prepared material has great application prospects in the field of degrading organic dyes.

The present invention relates to carbon nanocomposite sorbents. The present invention provides carbon nanocomposite sorbents, methods for making the same, and methods for separation of a pollutant from a gas that includes that pollutant. Various embodiments provide a method for reducing the mercury content of a mercury-containing gas.

The invention discloses a lithium sulfide / carbon composite nanometer material and a preparation method and application thereof. In a relatively typical embodiment, the method comprises the steps of fully mixing lithium sulfate and a carbon material precursor or a carbon material, and performing thermal treatment, wherein the thermal treatment condition comprises a temperature rising rate of 1-20 DEG C per minute, a constant temperature of 600 to 1000 DEG C for 2-12 hours in an inert atmosphere; and natural cooling of the material to a room temperature to acquire the lithium sulfide / carbon composite material. The invention provides a process for synthesizing the lithium sulfide / carbon nanocomposite material by reducing lithium sulfate with carbon, the process is simple and easy to operate, is high in controllability and low in cost, the raw materials are low in price and easy to get, moreover, the obtained product is the lithium sulfide / carbon nanocomposite material which is uniformly dispersed, has good performance and is controllable in morphology, the lithium sulfide / carbon nanocomposite material comprises a one-dimensional nanometer fiber, a two-dimensional nanosheet and the like, and the lithium sulfide / carbon nanocomposite material is high in conductivity and can be widely applied to an electrochemical energy storage device such as a lithium-sulfur battery.

The invention relates to carbon nanotube / polypyrrole composite sponge and a preparation method thereof, belonging to the field of the synthesis and application of carbon nanocomposites. The carbon nanotube / polypyrrole composite sponge is formed through stacking and winding composite tubes with microcosmic core-shell structures and has a porous structure, wherein each composite tube consists of a carbon nanotube and a uniform-thickness polypyrrole layer coated outside the carbon nanotube. The mass content of polypyrrole in the composite sponge is controllable; the composite sponge has good elasticity, good cyclic compression stability and excellent electrochemical properties; the carbon nanotube / polypyrrole composite sponge is prepared by the method which combines a chemical vapor deposition method, an adsorption composite method and an electrochemical polymerization method; the preparation method has ingenious conception and is simple and easy in operation.

The embodiment of the invention discloses a MoSxOy / carbon nanometer composite material, and a preparation method and application thereof, wherein in the MoSxOy / carbon nanometer composite material, x is greater than or equal to 2.5 but is smaller than or equal to 3.1; y is greater than or equal to 0.2 but is smaller than or equal to 0.7; on the basis of the total mass of the nanometer composite material, the mass percentage of the MoSxOy is 5 to 50 percent. When the prepared MoSxOy / carbon nanometer composite material is used as an electrocatalysis hydrogen evolution reaction catalyst, the current density during the overpotential of 300mV is equal to or higher than 150 mA / cm<2>; the performance has small differences from a commercial 20-percent Pt / C catalyst, or is even identical to that of the commercial 20-percent Pt / C catalyst. The performance is much better than that of the existing MoS2 composite material. In addition, the prepared MoSxOy / carbon nanometer composite material also has good catalysis stability; after the 8000 times of catalysis circulation, the current density is only lowered by 3 percent; excellent catalysis performance and circulation stability are shown.

The invention relates to a nitrogen-doped porous carbon / sulfur composite material and a preparing method and application thereof. The composite material is formed by a coaxial nitrogen-doped porous carbon material and elemental sulfur through compositing. The preparing method of the composite material includes the steps that a coaxial nitrogen-doped porous polymer / one-dimension nanometer composite material is subjected to high temperature treatment in a tube furnace under inert gas protection to form the coaxial nitrogen-doped porous carbon material, and then heat treatment compositing is carried out on the coaxial nitrogen-doped porous carbon material and the elemental sulfur to obtain the nitrogen-doped porous carbon / sulfur composite material. A lithium-sulfur battery based on the composite material is provided at the same time, the battery shows high specific discharge capacity, cycling stability and good rate performance.

The invention discloses a preparation method for a titanium dioxide (B)-graphene self-winding nano composite material and belongs to the technical field of carbon nano composite material preparation. The preparation method comprises the step of performing hydrothermal reaction on commercially available titanium dioxide powder and a graphene oxide solution which serve as raw materials to prepare the titanium dioxide (B)-graphene self-winding nano composite material. The preparation method disclosed by the invention has the characteristics of simplicity, easiness in operation, readily available raw material, low price, low production cost, convenience in popularization and application, suitability for industrial production and the like. A product prepared by the method disclosed by the invention is high in conductivity and high in structural stability and can bear charging and discharging under high current density. The preparation method can be widely used for preparation of the titanium dioxide (B)-graphene self-winding nano composite material. The product prepared by the method disclosed by the invention can be widely applied to the fields of photocatalysts, air purification, dye-sensitized solar batteries, lithium ion batteries and the like and is particularly suitable to be used as a cathode material of a powder type lithium ion battery.

The invention relates to a carbon nano composite and a preparation method thereof. The carbon nano composite comprises a carbon nano material and metal particles, wherein the carbon nano material is subjected to surface functionalization, and the metal particles are formed on the carbon nano material. The carbon nano composite can be used for removing pollutants in waste water, and a removal effect is significantly better than that of the existing nano material.

The invention discloses preparation and application of a Prussian blue / N-doped carbon nanometer composite material to the aspect of enzyme-free uric acid sensors. A preparation method of the Prussian blue / N-doped carbon nanometer composite material comprises the following three steps: acidizing treatment of a carbon nanometer composite material; preparation of a N-doped carbon nanometer composite material; preparation of the Prussian blue / N-doped carbon nanometer composite material. The prepared Prussian blue / N-doped carbon nanometer composite material is utilized for preparation of an enzyme-free uric acid sensor, has a very good three-dimensional space structure and a very good effect in catalyzing uric acid, and can be utilized for directly detecting uric acid under the circumstance that uricase is absent; compared with a common uricase sensor, the enzyme-free uric acid sensor prepared by utilizing the Prussian blue / N-doped carbon nanometer composite material is simpler, more economical and portable, long in storage period, and high in stability and anti-interference capability.

The invention relates to an iron-carbon nano composite electromagnetic wave absorption material and a preparation method thereof. Carbonyl iron, methane and acetylene serving as main raw materials are directly synthesized into the iron-carbon nano composite material in a gas-phase reaction device at the temperature of between 300 and 1,000 DEG C. The nano composite material has good stability and uniformity. The iron-carbon nano composite material is wrapped outside iron nano granules by nano-scale C to form a C film; and the iron-carbon nano composite material has the characteristics of good electromagnetic wave absorption performance, wide absorption coverage frequency range, strong corrosion and oxidation resistance and low cost, and is applicable to electromagnetic shielding in a radio communication system, electromagnetic radiation and leakage of equipment of high frequency prevention, microwave heating and the like, construction of microwave darkrooms and hiding technology.

The invention discloses a double-metal co-doped carbon nano-composite material and a preparation method thereof. The composite material is prepared from a carbon substrate and ferrocene-phenylalanine and transition metal except iron, which are co-assembled on the carbon substrate through a non-covalent bond, wherein the ferrocene-phenylalanine, the transition metal except the iron and the carbon substrate commonly form a raspberry-like nanosphere structure. The invention further discloses a double-metal-nitrogen-carbon nano-catalyst obtained by mixing the composite material with dicyanodiamide and carbonizing and further provides application of the double-metal-nitrogen-carbon nano-catalyst to catalytic oxygen reduction reaction. The preparation methods of the composite material and the catalyst have simple steps and low cost and are suitable for large-scale application. The double-metal-nitrogen-carbon nano-catalyst provided by the invention has excellent electrochemical performance and has good methanol toxin resistance and stability, so that the double-metal-nitrogen-carbon nano-catalyst has a good application prospect in the field of the catalytic oxygen reduction reaction.

This invention relates to a method of preparing an iron carbide / carbon nanocomposite catalyst containing potassium for high temperature Fischer-Tropsch (FT) synthesis reaction and the iron carbide / carbon nanocomposite catalyst prepared thereby, and a method of manufacturing a liquid hydrocarbon using the same and a liquid hydrocarbon manufactured thereby, wherein a porous carbon support is uniformly impregnated with an iron hydrate using melt infiltration, and potassium is also supported together via various addition processes, including a pre-addition process of a potassium salt which is ground upon impregnation with the iron hydrate, or a mid- or post-addition process of a potassium solution using incipient wetness impregnation after impregnation with the iron hydrate. Accordingly, the highly active iron carbide / potassium / carbon composite catalyst for high temperature FT reaction in which 5˜30 wt % of active iron carbide particles are supported on the porous carbon support can be obtained and is structurally stable to heat even in high temperature FT reaction of 300° C. or more, and liquid hydrocarbons can be selectively obtained at high yields.

The invention provides a method for preparing a carbon composite nano-material and the corresponding carbon composite nano-material. The method comprises the following steps: preparing carbon nano-tube film precursors; overlapping the carbon nano-tube film precursors to form a carbon nano-tube film with self-supporting performance; and arranging a metal film on the surface of the carbon nano-tube film. The carbon nano-tube film composite foil material obtained by the method has the excellent chemical and structural characteristics of a carbon nano-tube film and the high conductivity property of metal, and has the advantages of being thin, good in flexibility, good in conductivity and the like. Furthermore, the composite foil material is good in self-supporting performance, is easy to treat and process in the using process, and has a wide application prospect in the fields of electromagnetic shielding materials, functional smart materials, electrode materials and the like.

The invention discloses a preparation method of a metal organic framework derived iron sulfide@carbon nano composite material, and belongs to the technical field of lithium ion battery negative electrode materials. Fumaric acid and nitric acid molten iron are subjected to a hydrothermal reaction to obtain spindle-shaped MIL-88 nanoparticles, and then sulfur doping and calcining are performed to obtain a carbon-coated sulfur-doped core-shell structure iron sulfide@carbon nano composite material. The MIL-88(MOFs)-derived metal sulfide prepared by the preparation method disclosed by the inventionkeeps the frame structure of a precursor, and in the calcining process, an organic ligand in the metal organic framework material MIL-88 is cracked to form the core-shell structure of the carbon-coated iron sulfide core; the structure can inhibit the volume expansion of the electrode material in the charging and discharging process to adjust the integrity of the structure, and the formed activated carbon can improve the conductivity of the electrode material and improve the performance of the battery; and the preparation process has the advantages of low cost, simplicity and convenience in operation, environmental friendliness and the like, and has good realizability.

The invention relates to a silicon-carbon nanocomposite film. The silicon-carbon nanocomposite film comprises an independent support structure and a carbon nanomaterial covering the independent support structure adopting porous silicon nanowire arrays. A preparation method of the silicon-carbon nanocomposite film comprises steps as follows: (1), a silicon wafer is etched by an etching liquid, and the porous silicon nanowire arrays are formed on the surface of the silicon wafer; (2), hydrocarbon is taken as a carbon source, inert gas and / or hydrogen are / is taken as carrier gas, and the carbon nanomaterial is deposited on the porous silicon nanowire arrays with a chemical vapor deposition method, so that the silicon-carbon nanocomposite film is formed on the silicon wafer; (3), the silicon-carbon nanocomposite film on the silicon wafer is peeled off in an aqueous alkaline solution. The silicon-carbon nanocomposite film can be obtained with a simple method and is taken as an anode material, so that the anode material has high capacity, stable circulation, long cycling life and actual application value.

The invention relates to the technical field of software drivers, in particular to a carbon nanocomposite fiber based multi-stimulus response driver of a core-shell structure. Organic fibers with highstrength are adopted, the organic fibers are twisted and prepared into a yarn with a certain twist, the organic yarn is used as a core, a carbon nano film with a certain twist angle is wound througha concentric shaft coating device, and silicone rubber is infiltrated at the film to serve as an outer shell. The carbon nanocomposite fiber of the core-shell structure is twisted to form the yarn ofa spiral structure, the carbon nanotube composite yarn of the spiral structure is used as an electrically conductive fiber material, mechanical vibration output with high deformation and high frequency can be continuously generated after a certain amount of current passes through the fiber material, and the mechanical vibration output can be used as an efficient driver. In addition, being capableof responding quickly and efficiently to external electrothermal stimuli, the multi-stimulus response driver provided by the invention can also be used for driving by solvents and thermal stimuli, canbe used in different occasions according to needs, and has broad application prospects.

The invention relates to a lithium manganese phosphate / carbon nanocomposite as cathode material for rechargeable electrochemical cells with the general formula LixMnyM1-y(PO4)z / C where M is at least one other metal such as Fe, Ni, Co, Cr, V, Mg, Ca, Al, B, Zn, Cu, Nb, Ti, Zr, La, Ce, Y, x=0.8-1.1, y=0.5-1.0, 0.9<z<1.1, with a carbon content of 0.5 to 20% by weight, characterized by the fact that it is obtained by milling of suitable precursors of LixMnyM1-y(PO4)Z with electro-conductive carbon black having a specific surface area of at least 80 m2 / g or with graphite having a specific surface area of at least 9.5 m2 / g or with activated carbon having a specific surface area of at least 200 m2 / g. The invention also concerns a process for manufacturing said nanocomposite.

The invention relates to a preparation method and application of an iron carbide-cobalt / nitrogen doped carbon nano composite material. The preparation method specifically comprises the following stepsthat a, a mesoporous ordered KIT-6 silicon template is constructed; b, Co(NO3)2.6H2O and Fe(NO3)3.9H2O, melamine and P123 are injected into holes of the KIT-6 template; c, the mixture is subjected toannealing in an N2 environment to decompose Co(NO3)2.6H2O and Fe(NO3)3.9H2O to be subjected to a chemical reaction with carbon obtained by pyrolyzing the P123 and the melamine; and d, a product afterheat-treating is corroded with a NaOH solution. The obtained Fe3C-Co / NC composite material has a large specific surface area and quite good electrical conductivity and has quite good catalytic performance for oxygen reduction and electrolysis of water reaction of negative electrodes of alkaline fuel cells, and a new idea for rational design and construction of a multifunctional electrocatalyst isprovided.