The invention relates to a gas 
hydrate, in particular to a compound gas 
hydrate generation 
accelerant and a preparation method thereof. The 
accelerant is a 
mixed solution formed by dissolving nano dispersed particles and a gemini surfactant in water, wherein the nano dispersed particles are nano 
graphene particles, the purity degree (the 
mass fraction) of the nano dispersed particles is 99%, and the 
fineness of the nano dispersed particles ranges from 20 nm to 60 nm; the gemini surfactant adopts dimethylene-1,2-double (dodecyl dimethyl 
ammonium bromide)-C12-2-122Br-1; by taking the 
mixed solution as the total amount, in the prepared 
mixed solution, the concentration of the nano 
graphene particles is controlled from 0.08% to 1.2%, the concentration of the gemini surfactant is controlled from 0.03% to 0.1%, and the balance is water. The 
accelerant can be used to enhance the gas 
hydrate from the two processes of 
heat transmission and 
mass transfer in the 
generation process of the gas hydrate, reduces the 
induction time for gas hydrate generation, and improves generation efficiency of the gas hydrate; a 
nanofluid is more stable and has low possibility of coagulation under the compound condition of the nano dispersed particles and the gemini surfactant.