Nozzles and nebulizers that can be adjusted to produce an 
aerosol with optimum and reproducible quality based on the feedback information obtained using 
laser imaging techniques are provides. Two 
laser-based imaging techniques based on particle image velocimetry (PIV) and optical patternation are provided to map and contrast the size and velocity distributions for indirect and direct pneumatic nebulizations in 
plasma spectrometry. The flow field of droplets is illuminated by two pulses from a thin 
laser sheet with a known 
time difference. The scattering of the 
laser light from droplets is captured by a 
charge coupled device (CCD), providing two instantaneous images of the particles. Pointwise cross-correlation of the corresponding images yields a two-dimensional (2-D) velocity map of the 
aerosol velocity field. For 
droplet size distribution studies, the solution is doped with a fluorescent dye and both laser induced florescence (LIF) and 
Mie scattering images are captured simultaneously by two CCDs with the same 
field of view. The ratio of the LIF / Mie images provides relative 
droplet size information, which is then scaled by a point calibration method via a phase Doppler particle analyzer (PDPA). Two major outcomes are realized for three nebulization systems: 1) a direct injection high efficiency 
nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow 
nebulizer with a PFA Scott-type spray chamber. First, the 
central region of the 
aerosol cone from the direct injection nebulizers and the 
nebulizer-spray chamber arrangement comprise fast (>13 m / s and >8 m / s, respectively) and fine (<10 μm and <5 μm, respectively) droplets as compared to slow (<4 m / s) and large (>25 μm) droplets in the fringes. Second, the spray chamber acts as a 
momentum separator, rather than a 
droplet size selector, as it removes droplets having larger sizes or velocities. Smart-tunable nebulizers may utilize the measured 
momentum as a 
feedback control for adjusting certain operation properties of the nebulizer, such as operating conditions and / or critical dimensions.