The invention discloses energetic 
ion salts of 1-nitramine-2, 4-dimetridazloe and a preparation method thereof, and belongs to the technical field of energetic materials. The synthetic method is as follows: dissolving the 1-nitramine-2, 4-dimetridazloe in deionized water to obtain a pale yellow 
clear liquid, adding with stirring 0.5 time 
molar equivalent of 
potassium carbonate at 
room temperature for in-situ generation of 1-nitramine-2, 4-dimetridazloe 
potassium salt, then adding one time 
molar equivalent of 
ammonium chloride, hydrazine 
hydrochloride, 
guanidine hydrochloride, monoaminoguanidine 
hydrochloride, diaminoguanidine hydrochloride, triaminoguanidine hydrochloride and 3, 4, 5-triamino-1, 2, 4-
triazole hydrochloride, stirring to precipitate a pale yellow 
solid precipitate, after about 1 hour of reaction, filtering the pale yellow precipitate, further recrystallizing a coarse product by use of an 
acetone and 
diethyl ether mixed 
solvent to obtain a pure product. The synthetic method of the invention is simple, mild in condition and high in yield, and is environmental friendly due to using of the deionized water as a 
solvent. The density of involved seven salts is 1.70-1.93g cm<-3>, the 
detonation velocity calculated by EXPLO 
software is between 8370 and 9209 m s<-1>, the 
detonation pressure is between 29.3 and 40.5 GPa, the actually measured 
impact sensitivity is 4-40J, the 
detonation performance is excellent, and the energetic 
ion salts are potential energetic materials.