The invention discloses a novel antistatic white 
thermal control coating and a preparation method thereof; wherein the 
coating, from interior to exterior, comprises a surface treatment agent layer, a prime coat layer and a finishing coat layer; the prime coat layer and the finishing coat layer all use 
room temperature curing type organic 
silicone resin as a matrix resin; a plurality of sheet-shaped 
metal powders are crossedly overlapped and arranged in the prime coat layer, and one ends of part of the sheet-shaped 
metal powders extend to the finishing coat layer; and white 
zinc oxide is distributed in the finishing coat layer. The 
coating provided by the invention is white, thickness is 100-140mum, 
solar absorptance is 0.24-0.29, hemispherical 
emissivity is 0.85-0.91, total 
mass loss TML is less than 1%, a collected volatile condensable material CVCM is less than 0.1%, and volume resistivity rhoV is not less than 107 
ohm*m. The coating, through 100 times of high and low temperature heat cycle test in a temperature range from -100 to 100 DEG C, has advantages of non-
cracking, non-spalling, non-foaming and non-discoloring phenomena, stable 
optical property and good 
adhesion force, and can basically satisfy demand of a 
spacecraft on the antistatic white 
thermal control coating.