1540 results about "Succinimide" patented technology

A biodegradable lubricating oil composition especially useful as a gear oil employs a synthetic alcohol ester basestock formed from mono- and dipentaerythritol with certain mono- and dicarboxylic acids or dicarboxylic acid anhydrides and an effective amount of a polyoxyalkylene alcohol demulsifying agent, a combination of alkylated organic acid and ashless succinimide rust inhibitors and an ashless dithiocarbamate antiwear and extreme pressure agent.

This invention is directed to a new low molecular weight copolymer (The PIB / UAR copolymer) that may be prepared by reacting a low molecular weight polyisobutene (PIB) having less than about 32 carbon atoms with an unsaturated acidic reagent in the presence of a free radical initiator. No chain transfer agent is required to prepare the low molecular weight PIB / UAR copolymer. The PIB / UAR copolymer may be useful as is, or as an intermediate for (1) polysuccinimides, (2) detergents or dispersants for lube oil or fuels, (3) pour point depressants and (4) surface sizing agents for paper. The PIB / UAR copolymer may be used by itself or as the ester, amide, imide or metal salt derivative of the PIB / UAR copolymer. The PIB / UAR copolymer may be liquid at ambient temperature.

The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkylating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Ammonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100° C. to about 400° C. to produce N-methyl succinimide which is purified and hydrogenated to form NMP.

The invention discloses a polysaccharide-dopamine composite biogel and application of the biogel. A preparation method of the biogel comprises the following steps: dissolving 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride and N-hydroxy succinimide sodium in an MES (Methyl Ester Sulfonate) buffer solution with a pH value being 5-6 in an inert gas atmosphere so as to prepare an EDC (ethylcarbodiimide) mixed solution, subsequently adding the EDC mixed solution into a polysaccharide solution for reacting at 20-30 DEG C for 0.5-1 hour, then adding a dopamine solution for further reacting at 20-30 DEG C for 1-4 hours, dialyzing a reactant by taking distilled water as a dialyzate, taking trapped fluid for freezing and drying to obtain the polysaccharide-dopamine composite biogel. The polysaccharide-dopamine composite biogel is simple and effective in modification method and capable of increasing the surface viscidity of the cartilage tissue, reducing loss of therapeutic drugs or implanted cells and facilitating the repairing of the cartilage injury.

The present invention relates to a fast acting chemical treatment for preventing the generation of hydrogen sulfide odor by the microbial metabolic activities of sulfate reducing bacteria. Specifically, the invention relates to a method for preventing hydrogen sulfide odor generation in a sulfur species-containing aqueous medium, which includes adding to the aqueous medium an effective amount for the purpose of a sulfide scavenger treatment selected from the group consisting of glyoxal, triazine, n-chlorosuccinimide, and mixtures thereof.

The present invention provide a lubricant composition comprising a lubricant base oil, wherein said lubricant composition contains 0.08% by mass or less of zinc dithiophosphate or no zinc dithiophosphate as phosphorus amount for total amount of said lubricant composition, contacts metallic materials containing lead, and contains at least a kind of additive selected from a group consisting of following (A)˜(D): (A) organomolybdenum compounds (except molybdenum dithiophosphate); (B) borate ester and / or derivatives thereof; (C) organomolybdenum compounds, and borate ester and / or derivatives thereof; and (D) organomolybdenum compounds, and borated alkyl or alkenyl succinimide.

The present invention relates to an unleaded aminated aviation gasoline of high motor octane number (MON) and low toluene insoluble deposit formation containing an additive for controlling said deposits selected from the group consisting of high molecular weight hydrocarbyl amines, high molecular weight hydrocarbyl succinimide, high molecular weight hydrocarbyl substituted Mannish bases, and mixtures thereof, and optional carrier oil(s), to an additive concentrate for controlling toluene insoluble deposits, and to a method for producing the additive concentrate.

The invention discloses a preparation method of polydopamine modified alginic acid microspheres, which comprises the following steps of: under the protection of nitrogen, grafting dopamine to alginic acid by use of N-hydroxysuccinimide and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride; polymerizing the synthesized dopamine modified alginic acid under the slight alkaline condition to obtain a polydopamine modified alginic acid solution; dropwise adding the polydopamine modified alginic acid solution into a CaCl2 solution by a syringe; and aging to obtain polydopamine modified alginic acid microspheres. The method disclosed by the invention is simple in process, and the prepared modified alginic acid microspheres have higher swelling resistance and good mechanical properties.

The invention discloses a chromatographic medium using amino benzimidazole as a function ligand and a preparation method thereof. Hydrophilic porous microspheres are used as a chromatographic medium, activated by allyl bromide, and coupled with the amino benzimidazole to obtain a medium using the amino benzimidazole as the function ligand; dimethyl sulfoxide and the allyl bromide are sequentially added into a chromatographic matrix for activation; the activated chromatographic matrix is reacted with N-bromo-succinimide for bromo-alcoholization; the bromo-alcoholized chromatographic matrix is mixed with an amino benzimidazole solution for coupling the amino benzimidazole ligand; finally an aqueous ethanol amine solution is used for sealing unreacted bromo-alcoholized ends to obtain a hydrophobic charge induced chromatographic medium using the amino benzimidazole as the function group. The new chromatographic medium is simple in preparation process and high in antibody adsorption capacity, and has the characteristics of non salt dependent adsorption, can realize desorption and recovery by changing the solution pH to weak acid, and can be used for hydrophobic charge induction chromatographic separation of antibodies.

A fully formulated lubricating oil, lubricated surface, and lubricant additive concentrates for lubricants providing reduced sludge formation. The fully formulated lubricating oil composition has therein at least one succinimide dispersant derived from a polyalkylene compound having from about 50 to about 85% vinylidene double bonds in the compound, a metal containing detergent, at least one wear reducing agent, at least one antioxidant, and a hydrocarbon soluble titanium compound as a friction modifier. The lubricating oil composition is also substantially free of molybdenum compounds.

The present invention relates to an improved process for preparing polyalkenylsuccinimides having a sediment level less than 0.1 vol % comprising the steps of:(a) preparing a polyalkenyl derivative of an unsaturated acidic reagent by(i) reacting a polyalkylene with an unsaturated acidic reagent in the absence of a strong acid until at least 25% of the polyalkylene is converted to a polyalkenyl derivative of an unsaturated acidic reagent;(ii) continuing the reaction with an excess of the unsaturated acidic reagent in the presence of a strong acid to convert at least some of the unreacted polyalkylene to additional polyalkenyl derivative of an unsaturated acidic reagent; and(iii) removing the unreacted unsaturated acidic reagent;(b) reacting the unfiltered product of step (a) with a polyamine having at least one basic nitrogen atom;(c) diluting the product of step (b); and(d) subsequently filtering the polyalkenylsuccinimide product.

The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.

A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and / or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.

The invention discloses a biomedical adhesive for crosslinking reaction with wound skin tissues and a preparation method thereof. The biomedical adhesive is prepared by a method with following steps of firstly, using sodium periodate and oxidized sodium alginate to prepare dialdehyde sodium alginate, dialyzing, drying, and dissolving a product into an MES (methyl ester sulfonate) buffer solution; then, adding carboxymethyl chitosan, stirring and reacting for 6-12h, sequentially adding a certain amount of N-hydroxy succinimide, 1-(3-dimethylamino propyl)-3-ethylcarbodiimide hydrochloride and dopamine, continuing to stir and react for 8-24h under the nitrogen protection, dialyzing, freeze-drying, and storing in the shade and dry area. Before use, a wound is pretreated by hydrogen peroxide, the freeze-drying adhesive is dissolved by a PBS (poly butylenes succinate) buffer solution, and is immediately coated to the wound, and the wound can be adhered within 2-10min. The biomedical adhesive has the advantages that the adhering strength in the in-vitro wetting environment is stronger, the biocompatibility is good, the biodegradation is realized, and the curing of wounds is effectively promoted.

The present invention provides a lubricating oil composition with excellent torque capacity and shifting characteristics suitable for use as automatic or continuously variable transmission fluids, which composition comprises a base oil and, on the basis of the total mass of the composition, (A) a sulfonate detergent in an amount of 0.01 to 0.3 percent by mass in terms of metal (MeA); (B) a salicylate detergent in an amount of 0 or more than 0 and 0.1 percent by mass or less, in terms of metal (MeB); and (C) a boron-containing succinimide type ashless dispersant in an amount of 0.001 to 0.1 percent by mass in terms of boron (BoC); (MeB) / (MeA) being 0, or greater than 0 and 1.5 or less, and (MeA) / (BoC) being from 0.001 to 20.

The invention discloses a preparation method of a polyamide composite nanofiltration membrane, which comprises the following steps of partially hydrolyzing a polyacrylonitrile-based membrane under alkaline and heat treatment conditions, and activating the membrane in 1-ethyl-(3-dimethyl amino propyl) carbonyl diimine hydrochloride ethylene dichloride-hydrogen chloride (EDC-HCl) and N-hydroxyl succinimide (NHS); and then sequentially immersing the membrane in water phase monomer piperazine with low concentration and organic phase monomer benzenetricarbonyl trichloride, and the polyamide composite nanofiltration membrane is prepared by interfacial polymerization. The preparation method of the polyamide composite nanofiltration membrane has the advantages that compared with a traditional method, the method utilizes monomer solution with low concentration to perform the interfacial polymerization, high permeation flux can be obtained under ultra-low pressure (0.1MPa), and filter dye solution and saline solution have high separation selectivity.

The invention discloses a method for preparing a graphene oxide-chitosan composite material. The method includes the steps that a chitosan solution is prepared; secondly, a graphene oxide solution is prepared, a 1-ethyl-(3-dimethylaminopropyl)carbodiimide (EDC) solution is added into the graphene oxide solution during stirring, stirring reaction is conducted after dropwise addition, then an N-hydroxyl succinimide (NHS) solution is dropwise added into the graphene oxide solution, stirring reaction is conducted, and an activated hydroxyl graphene oxide solution is obtained; thirdly, the activated hydroxyl graphene oxide solution is dropwise added into the chitosan solution and stirred, the mixture is poured into a mould after being cooled to room temperature, and the cross-linked graphene oxide-chitosan composite material is obtained after freezing drying. The novel graphene oxide-chitosan composite material having an interface bonding function is provided, compared with non-cross-linked composite materials, mechanical properties of the composite material are greatly improved, and use of the composite material in the aspect of the bone induction technology is achieved.

This invention is directed to a new low molecular weight branched alkenyl succinic acid derivative that may be prepared by reacting a low molecular weight polyisobutene (PIB) having from about 8 to about 32 carbon atoms, and wherein at least about 50% of the olefinic bonds of the polyisobutene comprises methylvinylidene isomer plus tri-substituted isomer, with an unsaturated acidic reagent and method of making same, resulting in alkenyl succinic acid derivative isomers; and a low molecular weight branched alkenyl succinimide and method of making same.

A power transmission fluid composition, a power transmission containing the fluid, a method of operating a power transmission with the fluid and method of improving friction durability for a power transmission fluid. The power transmission fluid includes (a) a base oil and (b) an additive composition having therein (i) at least one ashless dispersant; (ii) a metal detergent providing greater than about 100 ppm metal in the power transmission fluid composition; (iii) a friction modifying amount of an imidazoline; (iv) a succinimide friction modifier; and (v) a non-hydroxy tertiary amine friction modifier other than (iii).

Lubricant compositions comprises a lubricant base oil and one or more compounds resulting the modification of a succinimide represented by formula (1) or (2) wherein R<1 >and R<2 >may be the same or different and are each independently a hydrocarbon group having 8 to 30 carbon atoms, R<3 >and R<4 >may be the same or different and are each independently a hydrocarbon group having 1 to 4 carbon atoms, R<5 >is hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, n is an integer from 1 to 7. The lubricant compositions have a long-lasting anti-shudder property, an enhanced transmission capacity for a wet clutch, and an excellent shifting property.

The invention relates to a fatty group polyester-polyamino acid copolymer with biology function and its synthesis method in the field of macromole biological medicine material technique. The block copolymer comprises: the two block copolymer (A) of fatty group polyester -polyamino acid with biology function and three block copolymer (B), and polyoxyethylene-fatty group polyester-polyamino acid three block copolymer (C). The synthesis method comprises: synthesizing the block copolymer of the carboxylic which is protected by benzyl, doing catalytic reduction to the palladium wood coal or hydrolyzing hydrogen bromide to generate the corresponding polymer with free carboxyl, then using NHS (N- hydroxyl succinimide-sauba) to active the flank carboxyl of the polyamino acid section, reacting it with short peptide, sugar or drug with RGD to obtain the fatty group polyester-polyamino acid copolymer with biology function.

An additive composition and lubricating fluid are disclosed that provide high steel-on-paper friction durability, good metal-metal extreme pressure performance characteristics and synchronizer performance. The lubricating fluid includes a base oil, a succinimide dispersant, a succinimide friction modifier, and a phosphonate. Also disclosed is a method for lubricating a dual clutch transmission employing a plurality of wet clutches, with the lubricating fluid of the disclosure.

The invention relates to the chemical field and particularly relates to a novel synthesis method for preparing a key intermediate 5-bromine-2-chlorine-4'-ethyoxyl diphenylmethane of a drug dapagliflozin for treating diabetes mellitus II. The preparation method comprises the following steps: enabling a starting raw material ortho-toluidine to firstly perform bromization and then perform chlorination after diazotization on a benzene ring with N-bromo-succinimide; then, in the presence of a halogenating agent, performing halogenating reaction of beta-position; and finally, performing Friedel-Crafts alkylation synthesis with phenetole, thereby obtaining the key intermediate. The preparation method is simple and convenient, economical and relatively high in reaction yield in each step, and suitable for industrial production.

The invention discloses an affinity chromatography medium employing tetrapeptide as a functional ligand and a preparation method of the affinity chromatography medium. The method comprises the following steps: adding dry matrix and allyl bromide to a dimethyl sulfoxide solution, activating, and reacting activating matrix with N-bromo succinimide; enabling bromo alcoholized matrix to react with hexamethylendiamine to obtain amino activating matrix; sequentially washing with deionized water, absolute ethyl alcohol and anhydrous N,N-dimethyl formamide, adding an N,N-dimethyl formamide solution containing tetrapeptide, 2-(7-azobenzotriazole)-N,N,N',N'-te-tramethyluronium hexafluorophosphate and N,N-diisopropylethylamine, and coupling a tetrapeptide ligand; and putting a medium coupled to tetrapeptide in a mixed liquid of sodium acetate and acetic anhydride to obtain the affinity chromatography medium employing tetrapeptide as the functional ligand. According to the novel chromatography medium developed by the method, a functional group is tetrapeptide composed of tyrosine, phenylalanine, arginine and histidine, and is designed on the basis of a protein A binding site of an antibody Fc segment; the antibody binding selectivity is greatly improved; and the affinity chromatography medium can be applied to efficient separation of an antibody.

This invention relates to a preparation method for poly-asparagic acid resin, which takes poly-pyrrolidine dione as the raw material to make crosslink poly-pyrrolidine dione with method of non-even phase suspended emulsion crosslink or non-even phase suspension crosslink and processes poly-asparagic acid resin by hydrolyzation characterizing that the crosslink poly-pyrrolidine dione is prepared by multi-section crosslink reaction, in which, the crosslinker is fed in for 2-4 times in equal volume and equal time interval, the crosslink poly-pyrrolidine dione and the resin are aged and crystallized and quickly dried, A ageing and crystallization process for 1-10 days under room temperature, B, quick drying process is carried out under -54-40deg.C.

The invention relates to an anti-tartar detersive for a quenching oil column of an ethylene unit. In order to solve the problems of the anti-tartar and cleaning of the quenching oil column, the invention provides the anti-tartar detersive for the quenching oil column. The anti-tartar detersive can inhibit the generation of dirt from the source; meanwhile, the detersive can also eliminate the generated dirt in the quenching oil column on line, thus providing necessary conditions for the long period operation of the ethylene unit. The anti-tartar detersive for the quenching oil column of the ethylene unit of the invention is characterized in that according to weight percentage, phenolic antioxidant is 1-18%, phosphorus metal ion deactivator is 8-20%, amine inhibitive substance is 5-35%, thiazolinyl succinimide dispersant is 2-18%, solvent is 30-70%; the substances are put into a container for heating, stirred and mixed evenly and cooled to room temperature, and then filtered to obtain the product.

A low-ash, low-phosphorus lubricant composition suitable for use in a stationary gas engine includes an oil of lubricating viscosity, 1.0 to 8 percent of a succinimide dispersant, 0.8 to 4.0 percent of a hindered, ester-substituted phenol antioxidant, and at least one metal or ammonium-containing sulfonate detergent or metal or ammonium-containing phenate detergent, in an amount which provides 0.1 to 3.0 percent by weight of said sulfonate or phenate moieties exclusive of the weight of the metal or ammonium moieties. The lubricant contains up to 0.08 percent by weight phosphorus and up to 0.2 percent sulfated ash.

The invention relates to methods for preparing and applying a modified polyaspartic acid scale inhibitor, which belong to the field of preparation and application of scale inhibitors. The method for preparing the modified polyaspartic acid scale inhibitor comprises the following step of: preparing polysuccinimide (PSI), polyaspartic acid (PASP) and modified polyaspartic acid (CSN-PASP). The scale inhibitor prepared by using the method has good adaptability at the temperature of 50-80 DEG C and the pH value ranging from 6.0 to 8.5. The modified polyaspartic acid scale inhibitor belongs to a polymer type scale inhibitor. A PASP molecule does not contain phosphorus, has no poison, does not destroy the ecological environment and has favorable biodegradability and water solubility, and the excellent scale inhibiting dispersion performance is particularly suitable for industrial water treatment. The aim for improving the scale inhibiting performance of the PASP is achieved by just adding a micromolecule substance in synthesis without changing other process conditions.

The invention relates to a lubricating oil composition of an engine, in particular to a lubricating oil composition for a heavy-load diesel engine, characterized by containing a great amount of hydrotreating base oil. The composition of the invention also contains suitable amounts of alkyl salicylates, sulfurized alkyl sulfide salts, sulphonate, macromolecular ashless dispersant, polyisobutylene-bis-succinimide ashless dispersant, zinc dialkyl dithiophosphate, phenolic antioxidant, amine-type antioxidant and sulfur-bearing antioxidant antiwear agent. The lubricating oil composition can satisfy the specification requirement of diesel engine oil CF-4, which is specified by GB11122-2006. The composition has simple prescription, low cost and convenient modulation.