This invention relates to certain 
sugar esters of phytosterols of formula (I). These esters are useful for topical application, and for the treatment of 
skin condition, including age spots, 
acne, loss of cellular antioxidants, collagen loss, loss of 
skin pliability, loss of 
skin suppleness, skin wrinkles including fine lines, oxidation, damage from 
radiation, malfunction of 
matrix metalloproteases, malfunction of tyrosinases, damage from free radicals, damage from UV, 
dry skin, xerosis, 
ichthyosis, 
dandruff, brownish spots, keratoses, 
melasma, lentigines, liver spots, 
pigmented spots, dark circles under the eyes, skin pigmentation including darkened skin, blemishes, oily skin, warts, eczema, pruritic skin, 
psoriasis, inflammatory dermatoses, topical 
inflammation, disturbed keratinization, skin changes associated with aging, nail or skin requiring cleansers, conditioning or treatment, and hair or 
scalp requiring shampooing or conditioning, and combinations thereof;Wherein,n=0, 1, 2, or 3; andR=H, —CH2OH, —CH(OH)—CH2OH, —CH(OH)—CH(OH)—CH2OH; andR1=
Substituent selected from a 
sapogenin, 
steroid, or 
terpenoid.