The invention relates to the technical field of materials for the 
light energy industry and the micro-
electronic industry and discloses a super-fine 
nickel-clad 
copper alloy wire and a manufacturing method of the super-fine 
nickel-clad 
copper alloy wire. The super-fine 
nickel-clad 
copper alloy wire comprises a super-fine 
copper wire, wherein a nickel film is arranged outside the super-fine 
copper wire, and the super-fine 
copper wire is mainly made of high-purity copper and is formed through 
smelting by adding modified elements to the high-purity copper. According to the super-fine nickel-clad 
copper alloy wire and the manufacturing method of the super-fine nickel-clad 
copper alloy wire, the problems that when drawing is conducted after plating, the film is uneven, wire rods are uneven and surface cracks occur after drawing due to the fact that the 
hardness of internal components is different from the 
hardness of external components and the 
plasticity of the internal components is different from the 
plasticity of the external component, and 
usability is affected can be avoided; meanwhile, the copper wire can be effectively prevented from being oxidized, and 
welding during application is facilitated; compared with an existing 
palladium-clad copper wire and an existing gold-clad copper wire, the nickel-clad copper wire has the 
advantage that material cost can be greatly reduced.