The invention belongs to the technical field of refractories for steel 
smelting furnaces, and in particular relates to a 
zirconium composite high-performance electrofused 
magnesium-
calcium zirconium brick and a manufacturing method thereof; the 
zirconium composite high-performance electrofused 
magnesium-
calcium zirconium 
brick comprises 5-10% of electrofused 
magnesium-
calcium zirconium sand with a partical size of 5-8mm, 20-35% of electrofused magnesium-calcium zirconium sand with a partical size of 2-5mm, 20-30% of electrofused magnesium-calcium zirconium sand with a partical size of 2-0.074mm, 10-15% of electrofused magnesium-calcium zirconium sand 
fine powder with a partical size of 0.074mm or less, 1-5% of electrofused magnesium sand with a partical size of 5-8mm, 1-10% of electrofused magnesium sand with a partical size of 2-5mm, 1-5% of electrofused magnesium sand with a partical size of 2-0.074mm, 5-10% of electrofused magnesium sand 
fine powder with a partical size of 0.074mm or less, 5-10% of electrofused magnesium sand super-
fine powder with a partical size of 0.037mm or less, 0.5-1.2% of calcium stabilized zirconia with a partical size of 0.5mm or less, 0.5-2% of 
metal calcium 
powder with a partical size of 0.088mm or less, 0.1-0.5% of 
silica fume with a partical size of 0.003mm or less and 2-5% of a binder. The method can obviously improve the physical and chemical performance indexes of the magnesium-calcium zirconium 
brick, anti-penetration, anti-
erosion, anti-
erosion and anti-spalling and other use performances of the magnesium-calcium zirconium brick can be improved, and most importantly, the magnesium-calcium zirconium brick can meet the requirements of current 
smelting conditions.