The invention provides a flexible thin-film solar photoelectric 
cell and a large-scale continuous automatic production method thereof. The solar photoelectric 
cell comprises an antireflection layer, a transparent upper 
electrode layer, an isolating layer, a window layer, a protective layer, an absorbing layer, a reflecting layer, a 
metal back 
electrode layer, an insulating layer, a substrate layer and a solder flux layer in sequence. The material of the antireflection layer is 
magnesium fluoride, the material of the transparent upper 
electrode layer is aluminum 
zinc oxide, the material of the isolating layer is intrinsic 
zinc oxide, the material of the window layer is 
zinc sulfide, the material of the protective layer is 
sulfur or zinc, the material of the absorbing layer is CIGS (
copper indium gallium diselenide) or CIAS (
copper indium aluminum 
diselenide), the material of the reflecting layer is aluminum, the material of the 
metal back electrode layer is 
copper-
molybdenum-
sodium alloy, the material of the insulating layer is 
titanium oxide, and the material of the substrate layer is stainless steel, copper, 
aluminum foil or 
polyimide film. The production method of the flexible thin-film solar photoelectric 
cell comprises 
sputtering layer by layer in a closed environment on a continuous automatic 
production line through a plurality of 
sputtering methods to form a multilayer structure. The large-scale continuous automatic production method provided by the invention has the advantages of high efficiency, high quality, and low cost.