The invention discloses a 
titanium-base tubular 
ruthenium dioxide 
coating membrane 
electrode and a preparation method thereof. According to the preparation method, a 
titanium filter 
pipe is utilized to replace a primary 
titanium plate to be taken as a matrix, and as numerous holes with the bore diameters of several microns are formed in the surface of the titanium filter 
pipe, compared with the normal 
titanium plate, the specific surface area is increased; and a firmly-bonded, uniformly-dispersed, surface-compacted and crack-free 
ruthenium dioxide 
thin layer is formed at the surface of the titanium filter 
pipe by utilizing a 
thermal oxidation method, and an 
oxide film can be firmly bonded with the titanium filter pipe after being subjected to the 
thermal oxidation. The 
electrode prepared by utilizing the preparation method has the advantages of firm 
coating structure, good electro-catalytic property and the like; the 
chlorine evolution potential of the 
ruthenium dioxide 
electrode is low, so that the 
chlorine is beneficially separated out; meanwhile, the operation of the preparation process is easy to control, the cost is low, the device requirements are relatively low, and the prepared electrode has double functions of electrochemical oxidation and membrane separation. Due to a 
diffusion action, the electrochemical oxidation efficiency can be improved, and meanwhile, the membrane 
pollution can be reduced due to the electrochemical oxidation, so that pollutants which are difficult to be biologically degraded can be more effectively processed.