The invention provides a battery 
coating film 
slurry, a battery separator, a secondary battery and their respective preparation methods. The preparation of the battery 
coating film 
slurry includes: providing a 
polymer unit, the 
polymer unit comprising vinylidene 
fluoride and a 
fluorine-containing 
polymer unit  , providing a nucleating agent, adding the nucleating agent during the 
polymerization of the 
polymerization unit to obtain a modified polymer; and preparing the battery 
coating film 
slurry based on the modified polymer.  Through the above technical solution, the present invention designs the battery coating film slurry, and adopts a non-aqueous 
system, which can not only bond the diaphragm and the 
pole piece together, improve the 
hardness of the battery, but also the 
crystal form of the polymer prepared  
Polar crystal transformation, more complete 
crystal structure and higher 
crystallinity, smaller 
swelling ratio, better bonding performance; the manufactured battery has smaller 
internal resistance and better cycle performance.  The water-based 
system is used to disperse the polymer, which solves the shortcomings of the oil-based 
system for preparing copolymers, gives full play to the advantages of water-based 
polymer coating products, and further improves the 
environmental protection effect.