The invention discloses a method for preparing super 
thermal isolation polymer materials from 
polymer nanometer hollow capsules. According to the method, firstly, hydrophilic and oleophilic macromolecular reversible addition fragmentation 
chain transfer reagents are used for preparing 
polymer nanometer capsules, then, inter-
capsule cross linking agents are prepared, finally, the inter-
capsule cross linking agents and the polymer nanometer 
capsule emulsion are mixed according to a 
mass ratio of capsule to inter-capsule cross linking agents of 2.5:1 to 0.8:1, the pH is regulated to be 3.0 to 6.8, the reaction lasts 30 minutes to 24 hours at the temperature being 60 to 90 DEG C, the 
emulsion is gelatinized, then, core 
paraffin wax in the nanometer capsules is replaced through 
tetrahydrofuran, and polymer nanometer porous materials are obtained through 
vacuum drying. The method has the advantages that the preparation process is simple, and the 
porosity and the pore size can be regulated through changing the 
solid content of the nanometer capsule 
emulsion, the consumption of etherified 
melamine formaldehyde resin and the self 
porosity of the nanometer hollow capsules. In addition, compared with the traditional 
thermal isolation materials, the porous materials have high 
mechanical strength.