The invention discloses an antibacterial protective environment-friendly 
composite polymer material and a preparation method and application thereof, wherein the 
composite polymer material comprises the following components by weight: 20 parts to 30 parts of benzyl 
quaternary ammonium salt, 50 parts to 75 parts of a biocompatible high-molecular 
polymer, 15 parts to 30 parts of modified nano metaloxide, 10 parts to 20 parts of nano 
metal particles, 30 parts to 40 parts of modified 
fiber, 25 parts to 45 parts of trisilanol 
ethyl ester silsesquioxane, 5 parts to 10 parts of a 
silane coupling agent, 3 parts to 5 parts of 
ammonium persulfate, 3 parts to 5 parts of 
dimethyl carbonate, 8 parts to 15 parts of 3-mercaptopropyl trimethoxy 
silane, and 2 parts to 3 parts of 
allyl glycidyl ether. Thematerial is capable of blocking and self-cleaning apatter or air with viruses, 
bacteria or microorganisms, is antibacterial, capable of killing viruses, capable of being repeatedly used, good in shrinkage resistance, high in elastic property and easy to degrade, and can be used for manufacturing window cloth, air conditioners, 
air purifiers, screen windows, clothes, trousers and masks.