The invention discloses an 
acid rain sampling, measuring and analyzing instrument which comprises 
metal shells. The 
metal shells are laminated and treated. A method for laminating and treating the 
metal shells includes steps of 1), sequentially inputting, by weight, 1-2 parts of dodecyl trimethyl 
ammonium bromide, 2.5 parts of aluminum 
oxide, 1.6 parts of 
dibutyl phthalate and 0.9 part of 
alum into 50 parts of deionized water and uniformly stirring the dodecyl trimethyl 
ammonium bromide, the aluminum 
oxide, the 
dibutyl phthalate, the 
alum and the deionized water to obtain first mixtures; 2), sequentially inputting, by weight, 15.5 parts of 
styrene, 9.9 parts of hydroxy propyl methylcelluloses, 1.8 parts of 
alkylphenol ethoxylate and 0.9 part of 
potassium tetraborate into the first mixtures, and continuing to stir the 
styrene, the hydroxy propyl methylcelluloses, the 
alkylphenol ethoxylate, the 
potassium tetraborate and the first mixtures until the 
styrene, the hydroxy propyl methylcelluloses, the 
alkylphenol ethoxylate, the 
potassium tetraborate and the first mixtures are sufficiently uniformly mixed with one another to obtain laminating and treating liquid; 3), placing the metal shells in the laminating and treating liquid, impregnating the metal shells in the laminating and treating liquid, taking the metal shells out of the laminating and treating liquid and then 
drying themetal shells. The 
acid rain sampling, measuring and analyzing instrument has the advantages that protective films cover the surfaces of the metal shells of the 
acid rain sampling, measuring and analyzing instrument, and accordingly the acid rain sampling, measuring and analyzing instrument is good in performance and high in 
surface smoothness.