The invention discloses a treatment method of complexing 
nickel wastewater. Compared with the prior art, Fe is loaded on granular 
active carbon, and a supported Fe2O3.FeO / GAC catalyst is prepared, a heterogeneously 
activated persulfate system generates 
sulfate radical free radicals with the strong oxidizing property to oxidize complex form 
heavy metals in the 
wastewater, by damaging the stable structure of complexing ions, the 
heavy metals are freed from complex, and the 
heavy metals are removed through a simple alkaline chemical 
precipitation method. The Fe2O3.FeO / GAC 
activated persulfate coupling system is established, the pH value of the 
wastewater is adjusted through the actual condition of the wastewater during wastewater treatment, a good 
treatment effect can be achieved, the catalyst still has good catalytic activity after being reused, and the wastewater treatment cost can be greatly reduced. A large amount of equipment investment and 
operating cost is not needed, materials are easy to take, and operation is simple. The 
active carbon carrier can be reused, resource reuse is achieved, and cost is reduced.